TY - JOUR
T1 - WO3 nanoparticles-based conformable pH sensor
AU - Santos, Lídia Sofia Leitão
AU - Neto, Joana P.
AU - Crespo, Ana
AU - Nunes, Daniela
AU - Costa, Nuno
AU - Fonseca, Isabel Maria de Figueiredo Ligeiro da
AU - Barquinha, Pedro Miguel Cândido
AU - Pereira, Luis Miguel Nunes
AU - Silva, Jorge
AU - Martins, Rodrigo Ferrão de Paiva
AU - Fortunato, Elvira Maria Correia
N1 - This work was funded by the Portuguese Science Foundation (FCT-MEC) through project EXCL/CTM-NAN/0201/2012, Strategic Project PEst-C/CTM/LA0025/2013-14, and the FCT-MCTES doctoral grants SFRH/BD/73810/2010 given to L.S. and SFRH/BD/76004/2011 given to J.N. Moreover, this work was also supported by E.F.'s ERC 2008 Advanced Grant (INVISIBLE contract number 228144).
PY - 2014/8/13
Y1 - 2014/8/13
N2 - pH is a vital physiological parameter that can be used for disease diagnosis and treatment as well as in monitoring other biological processes. Metal/metal oxide based pH sensors have several advantages regarding their reliability, miniaturization, and cost-effectiveness, which are critical characteristics for in vivo applications. In this work, WO3 nanoparticles were electrodeposited on flexible substrates over metal electrodes with a sensing area of 1 mm(2). These sensors show a sensitivity of -56.7 +/- 1.3 mV/pH, in a wide pH range of 9 to 5. A proof of concept is also demonstrated using a flexible reference electrode in solid electrolyte with a curved surface. A good balance between the performance parameters (sensitivity), the production costs, and simplicity of the sensors was accomplished, as required for wearable biomedical devices.
AB - pH is a vital physiological parameter that can be used for disease diagnosis and treatment as well as in monitoring other biological processes. Metal/metal oxide based pH sensors have several advantages regarding their reliability, miniaturization, and cost-effectiveness, which are critical characteristics for in vivo applications. In this work, WO3 nanoparticles were electrodeposited on flexible substrates over metal electrodes with a sensing area of 1 mm(2). These sensors show a sensitivity of -56.7 +/- 1.3 mV/pH, in a wide pH range of 9 to 5. A proof of concept is also demonstrated using a flexible reference electrode in solid electrolyte with a curved surface. A good balance between the performance parameters (sensitivity), the production costs, and simplicity of the sensors was accomplished, as required for wearable biomedical devices.
KW - electrodeposition
KW - flexible
KW - lightweight
KW - hydrothermal synthesis
KW - tungsten oxide nanoparticles
KW - pH sensor
KW - electrodeposition
KW - flexible
KW - hydrothermal synthesis
KW - lightweight
KW - pH sensor
KW - tungsten oxide nanoparticles
U2 - 10.1021/am501724h
DO - 10.1021/am501724h
M3 - Article
C2 - 25020126
SN - 1944-8244
VL - 6
SP - 12226
EP - 12234
JO - ACS Applied Materials & Interfaces
JF - ACS Applied Materials & Interfaces
IS - 15
ER -