Water soluble heterometallic potassium-dioxidovanadium(V) complexes as potential antiproliferative agents

Manas Sutradhar, Maria Alexandra Núncio de Carvalho Ramos Fernandes, Joana Silva, Kamran T. Mahmudov, M. Fatima C. Guedes da Silva, Armando J. L. Pombeiro

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Two water soluble heterometallic potassium-dioxidovanadium polymers, [KVO2(L-1)](n) (1) and [KVO2(L-2)(H2O)](n) (2) [H2L1 = (2,3-dihydroxybenzylidene)-2-hydroxybenzohydrazide and H2L2 = (2,3-dihydroxybenzylidene)benzohydrazide], have been synthesized and characterized by IR, NMR, elemental analysis and single crystal X-ray diffraction. The antiproliferative potentials of 1 and 2 were examined towards human colorectal carcinoma (HCT116), and lung (A549) and breast (MCF7) adenocarcinoma cell lines. 1 exhibits a high cytotoxic activity against colorectal carcinoma cells (HCT116), with IC50 lower than those for cisplatin. (C) 2015 Elsevier Inc All rights reserved.

Original languageEnglish
Pages (from-to)17-25
Number of pages9
JournalJournal of Inorganic Biochemistry
Volume155
DOIs
Publication statusPublished - Feb 2016

Keywords

  • Dioxidovanadium(V)
  • Heterometallic complex
  • X-ray structure
  • Antiproliferative agent
  • MONONUCLEAR OXIDOVANADIUM(V) COMPLEX
  • X-RAY-STRUCTURE
  • CRYSTAL-STRUCTURE
  • IN-VITRO
  • OXOVANADIUM(IV) COMPLEXES
  • COORDINATION CHEMISTRY
  • COPPER(II) COMPLEXES
  • VANADIUM COMPOUNDS
  • COBALT COMPLEXES
  • METAL-COMPLEXES

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