VUV photoabsorption by hexafluoropropene

S. Eden; Paulo Manuel Assis Loureiro Limão-vieira; S. V. Hoffmann; Nigel J. Mason

doi:10.1016/j.cplett.2003.08.029

VUV photoabsorption by hexafluoropropene

S. Eden, Paulo Manuel Assis Loureiro Limão-vieira, S. V. Hoffmann, Nigel J. Mason

DF – Departamento de Física

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The high-resolution photoabsorption spectrum of hexafluoropropene is reported in the wavelength range 115-320 nm (10.8-3.9 eV). Assignments are proposed for the features observed. The photolysis rate and lifetime of the molecule in the atmosphere are modelled as a function of altitude and compared with previous calculations made considering hexafluoropropene reactions with OH radicals.

Original language	English
Pages (from-to)	170-176
Number of pages	7
Journal	Chemical Physics Letters
Volume	379
Issue number	1-2
DOIs	https://doi.org/10.1016/j.cplett.2003.08.029
Publication status	Published - 19 Jan 2003

Keywords

hexafluoropropylene
hydroxyl radical
carbon
propylene
unclassified drug
spectral sensitivity
vibration
absorption spectroscopy
altitude
article
covalent bond
light absorption
molecule
photolysis

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10.1016/j.cplett.2003.08.029

http://www.scopus.com/record/display.uri?eid=2-s2.0-0141515216&origin=resultslist&sort=plf-f&src=s&st1

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abstract = "The high-resolution photoabsorption spectrum of hexafluoropropene is reported in the wavelength range 115-320 nm (10.8-3.9 eV). Assignments are proposed for the features observed. The photolysis rate and lifetime of the molecule in the atmosphere are modelled as a function of altitude and compared with previous calculations made considering hexafluoropropene reactions with OH radicals. ",

keywords = "hexafluoropropylene, hydroxyl radical, carbon, propylene, unclassified drug, spectral sensitivity, vibration, absorption spectroscopy, altitude, article, covalent bond, light absorption, molecule, photolysis",

author = "S. Eden and Lim{\~a}o-vieira, {Paulo Manuel Assis Loureiro} and Hoffmann, {S. V.} and Mason, {Nigel J.}",

year = "2003",

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doi = "10.1016/j.cplett.2003.08.029",

language = "English",

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T1 - VUV photoabsorption by hexafluoropropene

AU - Eden, S.

AU - Limão-vieira, Paulo Manuel Assis Loureiro

AU - Hoffmann, S. V.

AU - Mason, Nigel J.

PY - 2003/1/19

Y1 - 2003/1/19

N2 - The high-resolution photoabsorption spectrum of hexafluoropropene is reported in the wavelength range 115-320 nm (10.8-3.9 eV). Assignments are proposed for the features observed. The photolysis rate and lifetime of the molecule in the atmosphere are modelled as a function of altitude and compared with previous calculations made considering hexafluoropropene reactions with OH radicals.

AB - The high-resolution photoabsorption spectrum of hexafluoropropene is reported in the wavelength range 115-320 nm (10.8-3.9 eV). Assignments are proposed for the features observed. The photolysis rate and lifetime of the molecule in the atmosphere are modelled as a function of altitude and compared with previous calculations made considering hexafluoropropene reactions with OH radicals.

KW - hexafluoropropylene

KW - hydroxyl radical

KW - carbon

KW - propylene

KW - unclassified drug

KW - spectral sensitivity

KW - vibration

KW - absorption spectroscopy

KW - altitude

KW - article

KW - covalent bond

KW - light absorption

KW - molecule

KW - photolysis

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DO - 10.1016/j.cplett.2003.08.029

M3 - Article

VL - 379

SP - 170

EP - 176

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-2

ER -