VUV photo-absorption cross-section for CCl2F2

Paulo Manuel Assis Loureiro Limão-vieira; S. Eden; P. A. Kendall; Nigel J. Mason; S. V. Hoffmann

doi:10.1016/S0009-2614(02)01304-0

VUV photo-absorption cross-section for CCl2F2

Paulo Manuel Assis Loureiro Limão-vieira, S. Eden, P. A. Kendall, Nigel J. Mason, S. V. Hoffmann

DF – Departamento de Física

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The photo-absorption spectrum of CCl2F2 has been measured using synchrotron radiation in the range 5.5-11 eV (225 > λ > 110 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. The high resolution achieved has allowed vibrational series in one of these bands to be assigned for the first time. The measured VUV cross-sections may be used to derive the photolysis rate of CCl2F2 in the terrestrial atmosphere.

Original language	English
Pages (from-to)	535-541
Number of pages	7
Journal	Chemical Physics Letters
Volume	364
Issue number	5-6
DOIs	https://doi.org/10.1016/S0009-2614(02)01304-0
Publication status	Published - 16 Oct 2002

Access to Document

10.1016/S0009-2614(02)01304-0

Cite this

@article{27a943f2f4f04a1db46a9007714bee1e,

title = "VUV photo-absorption cross-section for CCl2F2",

abstract = "The photo-absorption spectrum of CCl2F2 has been measured using synchrotron radiation in the range 5.5-11 eV (225 > λ > 110 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. The high resolution achieved has allowed vibrational series in one of these bands to be assigned for the first time. The measured VUV cross-sections may be used to derive the photolysis rate of CCl2F2 in the terrestrial atmosphere. ",

author = "Lim{\~a}o-vieira, {Paulo Manuel Assis Loureiro} and S. Eden and Kendall, {P. A.} and Mason, {Nigel J.} and Hoffmann, {S. V.}",

year = "2002",

month = oct,

day = "16",

doi = "10.1016/S0009-2614(02)01304-0",

language = "English",

volume = "364",

pages = "535--541",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier Science B.V., Amsterdam.",

number = "5-6",

}

TY - JOUR

T1 - VUV photo-absorption cross-section for CCl2F2

AU - Limão-vieira, Paulo Manuel Assis Loureiro

AU - Eden, S.

AU - Kendall, P. A.

AU - Mason, Nigel J.

AU - Hoffmann, S. V.

PY - 2002/10/16

Y1 - 2002/10/16

N2 - The photo-absorption spectrum of CCl2F2 has been measured using synchrotron radiation in the range 5.5-11 eV (225 > λ > 110 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. The high resolution achieved has allowed vibrational series in one of these bands to be assigned for the first time. The measured VUV cross-sections may be used to derive the photolysis rate of CCl2F2 in the terrestrial atmosphere.

AB - The photo-absorption spectrum of CCl2F2 has been measured using synchrotron radiation in the range 5.5-11 eV (225 > λ > 110 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. The high resolution achieved has allowed vibrational series in one of these bands to be assigned for the first time. The measured VUV cross-sections may be used to derive the photolysis rate of CCl2F2 in the terrestrial atmosphere.

UR - http://www.scopus.com/record/display.uri?eid=2-s2.0-0037120806&origin=resultslist&sort=plf-f&src=s&st1

U2 - 10.1016/S0009-2614(02)01304-0

DO - 10.1016/S0009-2614(02)01304-0

M3 - Article

VL - 364

SP - 535

EP - 541

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 5-6

ER -

VUV photo-absorption cross-section for CCl2F2

Abstract

Access to Document

Other files and links

Fingerprint

Cite this