VUV photo-absorption cross-section for CCl2F2

Paulo Manuel Assis Loureiro Limão-vieira; S. Eden; P. A. Kendall; Nigel J. Mason; S. V. Hoffmann

doi:10.1016/S0009-2614(02)01304-0

VUV photo-absorption cross-section for CCl2F2

Paulo Manuel Assis Loureiro Limão-vieira, S. Eden, P. A. Kendall, Nigel J. Mason, S. V. Hoffmann

DF – Departamento de Física

Research output: Contribution to journal › Article

42 Citations (Scopus)

Abstract

The photo-absorption spectrum of CCl2F2 has been measured using synchrotron radiation in the range 5.5-11 eV (225 > λ > 110 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. The high resolution achieved has allowed vibrational series in one of these bands to be assigned for the first time. The measured VUV cross-sections may be used to derive the photolysis rate of CCl2F2 in the terrestrial atmosphere.

Original language	English
Pages (from-to)	535-541
Number of pages	7
Journal	Chemical Physics Letters
Volume	364
Issue number	5-6
DOIs	https://doi.org/10.1016/S0009-2614(02)01304-0
Publication status	Published - 16 Oct 2002

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Limão-vieira, P. M. A. L., Eden, S., Kendall, P. A., Mason, N. J., & Hoffmann, S. V. (2002). VUV photo-absorption cross-section for CCl2F2. Chemical Physics Letters, 364(5-6), 535-541. https://doi.org/10.1016/S0009-2614(02)01304-0

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AU - Limão-vieira, Paulo Manuel Assis Loureiro

AU - Eden, S.

AU - Kendall, P. A.

AU - Mason, Nigel J.

AU - Hoffmann, S. V.

PY - 2002/10/16

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AB - The photo-absorption spectrum of CCl2F2 has been measured using synchrotron radiation in the range 5.5-11 eV (225 > λ > 110 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. The high resolution achieved has allowed vibrational series in one of these bands to be assigned for the first time. The measured VUV cross-sections may be used to derive the photolysis rate of CCl2F2 in the terrestrial atmosphere.

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U2 - 10.1016/S0009-2614(02)01304-0

DO - 10.1016/S0009-2614(02)01304-0

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EP - 541

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

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