Toward Light-Controlled Supramolecular Peptide Dimerization

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Abstract

The selective photodeprotection of the NVoc-modified FGG tripeptide yields the transformation of its 1:1 receptor-ligand complex with cucurbit[8]uril into a homoternary FGG2@CB8 assembly. The resulting light-induced dimerization of the model peptide provides a tool for the implementation of stimuli-responsive supramolecular chemistry in biologically relevant contexts.

Original languageEnglish
Pages (from-to)8472-8478
JournalJournal of Organic Chemistry
Volume86
Issue number12
DOIs
Publication statusPublished - 18 Jun 2021

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