The alpha-C-H BDE in tetralin A time-resolved photoacoustic calorimetry study

José Artur Martinho Simões

doi:10.1007/s10973-009-0632-0

The alpha-C-H BDE in tetralin A time-resolved photoacoustic calorimetry study

José Artur Martinho Simões

Instituto de Tecnologia Química e Biológica António Xavier (ITQB)

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The alpha-C-H bond dissociation enthalpy (BDE) in tetralin (1,2,3,4-tetrahydronaphtalene) was determined using time-resolved photoacoustic calorimetry as 357.6 +/- 5.4 kJ mol(-1). This value is some 10 kJ mol(-1) higher than the only previous experimental determination but in remarkably good agreement with the alpha-C-H BDEs in the structurally related compounds such as 1-butene, cyclohexene, and ethylbenzene.

Original language	Unknown
Pages (from-to)	381-384
Journal	Journal Of Thermal Analysis And Calorimetry
Volume	100
Issue number	2
DOIs	https://doi.org/10.1007/s10973-009-0632-0
Publication status	Published - 1 Jan 2010

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10.1007/s10973-009-0632-0

Cite this

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title = "The alpha-C-H BDE in tetralin A time-resolved photoacoustic calorimetry study",

abstract = "The alpha-C-H bond dissociation enthalpy (BDE) in tetralin (1,2,3,4-tetrahydronaphtalene) was determined using time-resolved photoacoustic calorimetry as 357.6 +/- 5.4 kJ mol(-1). This value is some 10 kJ mol(-1) higher than the only previous experimental determination but in remarkably good agreement with the alpha-C-H BDEs in the structurally related compounds such as 1-butene, cyclohexene, and ethylbenzene.",

keywords = "ENTHALPY, TOOL, RATE CONSTANTS, RADICALS, ENERGETICS, PHASE",

author = "{Martinho Sim{\~o}es}, {Jos{\'e} Artur}",

note = "Borges dos Santos, Rui M.; Martinho Simoes, Jose A",

year = "2010",

month = jan,

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doi = "10.1007/s10973-009-0632-0",

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journal = "Journal Of Thermal Analysis And Calorimetry",

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T1 - The alpha-C-H BDE in tetralin A time-resolved photoacoustic calorimetry study

AU - Martinho Simões, José Artur

N1 - Borges dos Santos, Rui M.; Martinho Simoes, Jose A

PY - 2010/1/1

Y1 - 2010/1/1

N2 - The alpha-C-H bond dissociation enthalpy (BDE) in tetralin (1,2,3,4-tetrahydronaphtalene) was determined using time-resolved photoacoustic calorimetry as 357.6 +/- 5.4 kJ mol(-1). This value is some 10 kJ mol(-1) higher than the only previous experimental determination but in remarkably good agreement with the alpha-C-H BDEs in the structurally related compounds such as 1-butene, cyclohexene, and ethylbenzene.

AB - The alpha-C-H bond dissociation enthalpy (BDE) in tetralin (1,2,3,4-tetrahydronaphtalene) was determined using time-resolved photoacoustic calorimetry as 357.6 +/- 5.4 kJ mol(-1). This value is some 10 kJ mol(-1) higher than the only previous experimental determination but in remarkably good agreement with the alpha-C-H BDEs in the structurally related compounds such as 1-butene, cyclohexene, and ethylbenzene.

KW - ENTHALPY

KW - TOOL

KW - RATE CONSTANTS

KW - RADICALS

KW - ENERGETICS

KW - PHASE

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DO - 10.1007/s10973-009-0632-0

M3 - Article

SN - 1388-6150

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JO - Journal Of Thermal Analysis And Calorimetry

JF - Journal Of Thermal Analysis And Calorimetry

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