Synthesis of γ-amino acid analogues from natural α-amino acids by a radical pathway

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Abstract

New γ-amino esters and amides were prepared by a radical 1,4-addition of carbon radicals to acrylic derivatives. α-Amino acids derivatives holding chiral auxiliaries as radical precursors and different chiral olefins were used and chiral induction on the C-γ center was discussed.

Original languageEnglish
Pages (from-to)243-246
Number of pages4
JournalAmino Acids
Volume32
Issue number2
DOIs
Publication statusPublished - 1 Feb 2007

Keywords

  • Amino acids and derivatives
  • Radicals
  • Synthesis

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