Self-assembly of a hydrophobically modified naphthalene-labeled poly(acrylic acid) polyelectrolyte in water:Organic solvent mixtures followed by steady-state and time-resolved fluorescence

Telma Costa; M. G. Miguel; Björn Lindman; Karin Schillén; J. C. Lima; J. Seixas De Melo

doi:10.1021/jp046589w

Self-assembly of a hydrophobically modified naphthalene-labeled poly(acrylic acid) polyelectrolyte in water:Organic solvent mixtures followed by steady-state and time-resolved fluorescence

Telma Costa, M. G. Miguel, Björn Lindman, Karin Schillén, J. C. Lima, J. Seixas De Melo

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The solution properties of hydrophobically modified napthalene (Np)-labeled poly(acrylic acid) (PAA) polyelectrolytes were investigated in water:organic solvent mixtures. The photophysical behavior of the polymers was also investigated using steady-state and time-resolved fluorescence. The emission spectra of the high-labeled Np PAA showed the presence of monomer and excimer bands, while with the low-labeled polymer only monomer emission was found. It was also found that the decay times were dependent on the water content of the mixture.

Original language	English
Pages (from-to)	3243-3251
Number of pages	9
Journal	Journal of Physical Chemistry B
Volume	109
Issue number	8
DOIs	https://doi.org/10.1021/jp046589w
Publication status	Published - 3 Mar 2005

Keywords

Pyrene
Fluorescence
Pyrene excimer

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10.1021/jp046589wLicence: CC BY-NC

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title = "Self-assembly of a hydrophobically modified naphthalene-labeled poly(acrylic acid) polyelectrolyte in water:Organic solvent mixtures followed by steady-state and time-resolved fluorescence",

abstract = "The solution properties of hydrophobically modified napthalene (Np)-labeled poly(acrylic acid) (PAA) polyelectrolytes were investigated in water:organic solvent mixtures. The photophysical behavior of the polymers was also investigated using steady-state and time-resolved fluorescence. The emission spectra of the high-labeled Np PAA showed the presence of monomer and excimer bands, while with the low-labeled polymer only monomer emission was found. It was also found that the decay times were dependent on the water content of the mixture.",

keywords = "Pyrene, Fluorescence, Pyrene excimer",

author = "Telma Costa and Miguel, {M. G.} and Bj{\"o}rn Lindman and Karin Schill{\'e}n and Lima, {J. C.} and {De Melo}, {J. Seixas}",

year = "2005",

month = mar,

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doi = "10.1021/jp046589w",

language = "English",

volume = "109",

pages = "3243--3251",

journal = "Journal of Physical Chemistry B",

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publisher = "ACS - American Chemical Society",

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Self-assembly of a hydrophobically modified naphthalene-labeled poly(acrylic acid) polyelectrolyte in water:Organic solvent mixtures followed by steady-state and time-resolved fluorescence. / Costa, Telma; Miguel, M. G.; Lindman, Björn et al.
In: Journal of Physical Chemistry B, Vol. 109, No. 8, 03.03.2005, p. 3243-3251.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Self-assembly of a hydrophobically modified naphthalene-labeled poly(acrylic acid) polyelectrolyte in water:Organic solvent mixtures followed by steady-state and time-resolved fluorescence

AU - Costa, Telma

AU - Miguel, M. G.

AU - Lindman, Björn

AU - Schillén, Karin

AU - Lima, J. C.

AU - De Melo, J. Seixas

PY - 2005/3/3

Y1 - 2005/3/3

N2 - The solution properties of hydrophobically modified napthalene (Np)-labeled poly(acrylic acid) (PAA) polyelectrolytes were investigated in water:organic solvent mixtures. The photophysical behavior of the polymers was also investigated using steady-state and time-resolved fluorescence. The emission spectra of the high-labeled Np PAA showed the presence of monomer and excimer bands, while with the low-labeled polymer only monomer emission was found. It was also found that the decay times were dependent on the water content of the mixture.

AB - The solution properties of hydrophobically modified napthalene (Np)-labeled poly(acrylic acid) (PAA) polyelectrolytes were investigated in water:organic solvent mixtures. The photophysical behavior of the polymers was also investigated using steady-state and time-resolved fluorescence. The emission spectra of the high-labeled Np PAA showed the presence of monomer and excimer bands, while with the low-labeled polymer only monomer emission was found. It was also found that the decay times were dependent on the water content of the mixture.

KW - Pyrene

KW - Fluorescence

KW - Pyrene excimer

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U2 - 10.1021/jp046589w

DO - 10.1021/jp046589w

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AN - SCOPUS:14844339704

SN - 1520-6106

VL - 109

SP - 3243

EP - 3251

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 8

ER -

Self-assembly of a hydrophobically modified naphthalene-labeled poly(acrylic acid) polyelectrolyte in water:Organic solvent mixtures followed by steady-state and time-resolved fluorescence

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Keywords

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