Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

Lorena Postigo Galindo; Maria Ventura; Tomás Cuenca; Gerardo Jiménez; Beatriz Royo Cantabrana

doi:10.1039/c4cy00965g

Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

Lorena Postigo Galindo, Maria Ventura, Tomás Cuenca, Gerardo Jiménez, Beatriz Royo Cantabrana

Instituto de Tecnologia Química e Biológica António Xavier (ITQB)

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

A moisture-tolerant cyclopentadienyl-silsesquioxane titanium complex efficiently catalyses the selective oxidation of various types of sulfides to either sulfoxides (TOFs up to 32 530 h^-1) or sulfones with H₂O₂ (30% in water) under mild conditions.

Original language	English
Pages (from-to)	320-324
Number of pages	5
Journal	Catalysis Science and Technology
Volume	5
Issue number	1
DOIs	https://doi.org/10.1039/c4cy00965g
Publication status	Published - 2015

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10.1039/c4cy00965g

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title = "Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst",

abstract = "A moisture-tolerant cyclopentadienyl-silsesquioxane titanium complex efficiently catalyses the selective oxidation of various types of sulfides to either sulfoxides (TOFs up to 32 530 h-1) or sulfones with H2O2 (30% in water) under mild conditions.",

author = "{Postigo Galindo}, Lorena and Maria Ventura and Tom{\'a}s Cuenca and Gerardo Jim{\'e}nez and Cantabrana, {Beatriz Royo}",

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AU - Postigo Galindo, Lorena

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AU - Cuenca, Tomás

AU - Jiménez, Gerardo

AU - Cantabrana, Beatriz Royo

PY - 2015

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AB - A moisture-tolerant cyclopentadienyl-silsesquioxane titanium complex efficiently catalyses the selective oxidation of various types of sulfides to either sulfoxides (TOFs up to 32 530 h-1) or sulfones with H2O2 (30% in water) under mild conditions.

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DO - 10.1039/c4cy00965g

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JO - Catalysis Science and Technology

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