Physical-chemical and electrical characterizations of membranes modified with room temperature ionic liquids: Age effect

S. Bijani; R. Fortunato; M. V. Martínez de Yuso; F. A. Heredia-Guerrero; E. Rodríguez-Castellón; I. Coelhoso; J. Crespo; J. Benavente

doi:10.1016/j.vacuum.2009.03.024

Physical-chemical and electrical characterizations of membranes modified with room temperature ionic liquids: Age effect

S. Bijani, R. Fortunato, M. V. Martínez de Yuso, F. A. Heredia-Guerrero, E. Rodríguez-Castellón, I. Coelhoso, J. Crespo, J. Benavente

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Physical-chemical characterization of supported liquid membranes (SLMs), that is, a porous structure containing room temperature ionic liquids (RTILs) was carried out by analyzing XPS and FTIR spectra, while determination of cation transport number from concentration potentials measured with the membranes in contact with NaCl Solutions gives transport/electrical information. SLMs filled with two different RTILs (C8MIMPF6 and C10MIMBF4) were studied, and the comparison of results obtained with fresh and aged membranes seems to indicate ion transport modification for aged samples at relatively high NaCl concentrations, which could be associated to changes in the polymer matrix-RTILs interactions. (C) 2009 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1283-1286
Number of pages	4
Journal	Vacuum
Volume	83
Issue number	10
DOIs	https://doi.org/10.1016/j.vacuum.2009.03.024
Publication status	Published - 16 Jun 2009

Access to Document

10.1016/j.vacuum.2009.03.024

Cite this

@article{4c8ba2c4cd18473688e22930ea0933a4,

title = "Physical-chemical and electrical characterizations of membranes modified with room temperature ionic liquids: Age effect",

abstract = "Physical-chemical characterization of supported liquid membranes (SLMs), that is, a porous structure containing room temperature ionic liquids (RTILs) was carried out by analyzing XPS and FTIR spectra, while determination of cation transport number from concentration potentials measured with the membranes in contact with NaCl Solutions gives transport/electrical information. SLMs filled with two different RTILs (C8MIMPF6 and C10MIMBF4) were studied, and the comparison of results obtained with fresh and aged membranes seems to indicate ion transport modification for aged samples at relatively high NaCl concentrations, which could be associated to changes in the polymer matrix-RTILs interactions. (C) 2009 Elsevier Ltd. All rights reserved.",

keywords = "membranes, number, liquid, RTILs, ATR-FTIR, XPS, ray, transport, Transport, Supported, photoelectron-spectroscopy",

author = "S. Bijani and R. Fortunato and {de Yuso}, {M. V. Mart{\'i}nez} and Heredia-Guerrero, {F. A.} and E. Rodr{\'i}guez-Castell{\'o}n and I. Coelhoso and J. Crespo and J. Benavente",

year = "2009",

month = jun,

day = "16",

doi = "10.1016/j.vacuum.2009.03.024",

language = "English",

volume = "83",

pages = "1283--1286",

journal = "Vacuum",

issn = "0042-207X",

publisher = "Elsevier",

number = "10",

}

TY - JOUR

T1 - Physical-chemical and electrical characterizations of membranes modified with room temperature ionic liquids

T2 - Age effect

AU - Bijani, S.

AU - Fortunato, R.

AU - de Yuso, M. V. Martínez

AU - Heredia-Guerrero, F. A.

AU - Rodríguez-Castellón, E.

AU - Coelhoso, I.

AU - Crespo, J.

AU - Benavente, J.

PY - 2009/6/16

Y1 - 2009/6/16

N2 - Physical-chemical characterization of supported liquid membranes (SLMs), that is, a porous structure containing room temperature ionic liquids (RTILs) was carried out by analyzing XPS and FTIR spectra, while determination of cation transport number from concentration potentials measured with the membranes in contact with NaCl Solutions gives transport/electrical information. SLMs filled with two different RTILs (C8MIMPF6 and C10MIMBF4) were studied, and the comparison of results obtained with fresh and aged membranes seems to indicate ion transport modification for aged samples at relatively high NaCl concentrations, which could be associated to changes in the polymer matrix-RTILs interactions. (C) 2009 Elsevier Ltd. All rights reserved.

AB - Physical-chemical characterization of supported liquid membranes (SLMs), that is, a porous structure containing room temperature ionic liquids (RTILs) was carried out by analyzing XPS and FTIR spectra, while determination of cation transport number from concentration potentials measured with the membranes in contact with NaCl Solutions gives transport/electrical information. SLMs filled with two different RTILs (C8MIMPF6 and C10MIMBF4) were studied, and the comparison of results obtained with fresh and aged membranes seems to indicate ion transport modification for aged samples at relatively high NaCl concentrations, which could be associated to changes in the polymer matrix-RTILs interactions. (C) 2009 Elsevier Ltd. All rights reserved.

KW - membranes

KW - number

KW - liquid

KW - RTILs

KW - ATR-FTIR

KW - XPS

KW - ray

KW - transport

KW - Transport

KW - Supported

KW - photoelectron-spectroscopy

U2 - 10.1016/j.vacuum.2009.03.024

DO - 10.1016/j.vacuum.2009.03.024

M3 - Article

SN - 0042-207X

VL - 83

SP - 1283

EP - 1286

JO - Vacuum

JF - Vacuum

IS - 10

ER -