Abstract
Structural assignment of dimers obtained during irradiation of methyl dehydroabietate[3], methyl deisopropyldehydroabietate[2], and 10α-methyl-13-deisopropyldehydroabietate [1] was achieved by using a combination of nOe difference spectroscopy, 3-D molecular modelling, and X-ray crystallography. The configuration of the a/b ring junction appears to be crucial in the stereochemical outcome of the dimerization reaction.
Original language | English |
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Pages (from-to) | 247-253 |
Number of pages | 7 |
Journal | Journal Of Natural Products |
Volume | 54 |
Issue number | 1 |
DOIs | |
Publication status | Published - 1 Jan 1991 |