Photochemistry of Supramolecular systems: Size and charge effects in the photoaquation of adducts of the Hexacyanocobaltate (III) anion with polyammonium Macrocyclic receptors

Fernando Jorge da Silva Pina; Luca Moggi; M. Francesca  Manfrin; Vincenzo Balzani; M. W. Hosseini; J. M. Lehn

Photochemistry of Supramolecular systems: Size and charge effects in the photoaquation of adducts of the Hexacyanocobaltate (III) anion with polyammonium Macrocyclic receptors

Fernando Jorge da Silva Pina, Luca Moggi, M. Francesca Manfrin, Vincenzo Balzani, M. W. Hosseini, J. M. Lehn

DQ - Departamento de Química

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

The quantum yield of CN- release from adducts of Co(CN)3- 6 with polyammonium macrolcyclic receptors depends in a critical way on the size but not on the charge of the receptor. These results suggest that Co(CN)3- 6 resides in, or close to, the macrocyclic cavity when the receptor has an appropriate size.

Original language	English
Pages (from-to)	65-67
Number of pages	3
Journal	Gazzetta Chimica Italiana
Volume	119
Issue number	1
Publication status	Published - Jan 1989

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@article{1605b96d29fa4be981a5a55dbd71f329,

title = "Photochemistry of Supramolecular systems: Size and charge effects in the photoaquation of adducts of the Hexacyanocobaltate (III) anion with polyammonium Macrocyclic receptors",

abstract = "The quantum yield of CN- release from adducts of Co(CN)3- 6 with polyammonium macrolcyclic receptors depends in a critical way on the size but not on the charge of the receptor. These results suggest that Co(CN)3- 6 resides in, or close to, the macrocyclic cavity when the receptor has an appropriate size.",

author = "Pina, {Fernando Jorge da Silva} and Luca Moggi and Manfrin, {M. Francesca} and Vincenzo Balzani and Hosseini, {M. W.} and Lehn, {J. M.}",

year = "1989",

month = jan,

language = "English",

volume = "119",

pages = "65--67",

journal = "Gazzetta Chimica Italiana",

number = "1",

}

Photochemistry of Supramolecular systems: Size and charge effects in the photoaquation of adducts of the Hexacyanocobaltate (III) anion with polyammonium Macrocyclic receptors. / Pina, Fernando Jorge da Silva; Moggi, Luca; Manfrin, M. Francesca et al.
In: Gazzetta Chimica Italiana, Vol. 119, No. 1, 01.1989, p. 65-67.

Research output: Contribution to journal › Comment/debate › peer-review

TY - JOUR

T1 - Photochemistry of Supramolecular systems

T2 - Size and charge effects in the photoaquation of adducts of the Hexacyanocobaltate (III) anion with polyammonium Macrocyclic receptors

AU - Pina, Fernando Jorge da Silva

AU - Moggi, Luca

AU - Manfrin, M. Francesca

AU - Balzani, Vincenzo

AU - Hosseini, M. W.

AU - Lehn, J. M.

PY - 1989/1

Y1 - 1989/1

N2 - The quantum yield of CN- release from adducts of Co(CN)3- 6 with polyammonium macrolcyclic receptors depends in a critical way on the size but not on the charge of the receptor. These results suggest that Co(CN)3- 6 resides in, or close to, the macrocyclic cavity when the receptor has an appropriate size.

AB - The quantum yield of CN- release from adducts of Co(CN)3- 6 with polyammonium macrolcyclic receptors depends in a critical way on the size but not on the charge of the receptor. These results suggest that Co(CN)3- 6 resides in, or close to, the macrocyclic cavity when the receptor has an appropriate size.

M3 - Comment/debate

VL - 119

SP - 65

EP - 67

JO - Gazzetta Chimica Italiana

JF - Gazzetta Chimica Italiana

IS - 1

ER -

Photochemistry of Supramolecular systems: Size and charge effects in the photoaquation of adducts of the Hexacyanocobaltate (III) anion with polyammonium Macrocyclic receptors

Abstract

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