Oxidative inactivation of NiFeSe hydrogenase

Pierre Ceccaldi, Marta C. Marques, Vincent Fourmond, Ines Antunes Pereira, Christophe Léger

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14 Citations (Scopus)

Abstract

We propose a resolution to the paradox that spectroscopic studies of NiFeSe hydrogenase have not revealed any major signal attributable to NiIII states formed upon reaction with O2, despite the fact that two inactive states are formed upon either aerobic or anaerobic oxidation.

Original languageEnglish
Pages (from-to)14223-14226
Number of pages4
JournalChemical Communications
Volume51
Issue number75
DOIs
Publication statusPublished - 29 Jul 2015

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Ceccaldi, P., Marques, M. C., Fourmond, V., Pereira, I. A., & Léger, C. (2015). Oxidative inactivation of NiFeSe hydrogenase. Chemical Communications, 51(75), 14223-14226. https://doi.org/10.1039/c5cc05930e