Oxidation of pinane using zeolite encapsulated metal phthalocyanine catalysts

A. A. Valente, J. Vital

Research output: Contribution to journalConference articlepeer-review

11 Citations (Scopus)

Abstract

The oxidation of cis-pinane by t-butyl hydroperoxide is catalysed by iron and cobalt phthalocyanines encapsulated in NaY zeolites. The main reaction product is 2-pinane hydroperoxide which in turn decomposes giving substituted cyclobutanes. In contrast to the reaction in homogeneous phase, products of oxidation on C3 and C4 are not observed.

Original languageEnglish
Pages (from-to)461-468
Number of pages8
JournalStudies in Surface Science and Catalysis
Volume108
Publication statusPublished - 1 Jan 1997
Event4th International Symposium on Heterogeneous Catalysis and Fine Chemicals - Bsel, Switzerland
Duration: 8 Sep 199612 Sep 1996

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