We report on structural, electronic, and optical properties of boron-doped, hydrogenated nanocrystalline silicon (nc-Si:H) thin films deposited by plasma-enhanced chemical vapor deposition (PECVD) at a substrate temperature of 150°C. Film properties were studied as a function of trimethylboron-to-silane ratio and film thickness. The film thickness was varied in the range from 14 to 100 nm. The conductivity of 60 nm thick films reached a peak value of 0.07 S/cm at a doping ratio of 1%. As a result of amorphization of the film structure, which was indicated by Raman spectra measurements, any further increase in doping reduced conductivity. We also observed an abrupt increase in conductivity with increasing film thickness ascribed to a percolation cluster composed of silicon nanocrystallites. The absorption loss of 25% at a wavelength of 400 nm was measured for the films with optimized conductivity deposited on glass and glass/ZnO:Al substrates. A low-leakage, blue-enhancedp-i-nphotodiode with an nc-Sip-layer was also fabricated and characterized.
|Title of host publication||Materials Research Society Symposium|
|Publication status||Published - 1 Jan 2009|
|Event||2009 MRS Spring Meeting - |
Duration: 1 Jan 2009 → …
|Conference||2009 MRS Spring Meeting|
|Period||1/01/09 → …|
DEE Group Author, & Vieira, M. M. D. A. C. (2009). Optimization of p-type Nanocrystalline Silicon Thin Films for Solar Cells and Photodiodes. In Materials Research Society Symposium (pp. 1153-A06-02) https://doi.org/10.1557/PROC-1153-A06-02