Abstract
A new enantioselective/inverse phase transfer catalysis (IPTC) reaction for the Markovnikov hydration of double bounds by an oxymercuration-demercuration reaction with cyclodextrins as catalysts was disclosed. Moderate ee (up to 32%) and yields (14-60%) were obtained for allylic amines and protected allylic alcohols as starting materials.
Original language | English |
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Pages (from-to) | 11986-11990 |
Number of pages | 5 |
Journal | Tetrahedron |
Volume | 61 |
Issue number | 50 |
DOIs | |
Publication status | Published - 12 Dec 2005 |
Keywords
- Cyclodextrin
- Hydration
- IPTC
- Oxymercuration
- Reduction