TY - JOUR
T1 - Modelling of uncatalysed and barium catalysed NO reduction by activated carbon
AU - Carabineiro, Sónia A.
AU - Fernandes, Francisco B.
AU - Vital, Joaquim Silvério
AU - Ramos, Ana M.
AU - Silva, Isabel F.
N1 - S6nia Carabineiro is grateful to Funda~o para a Ci8ncia e Tecnologia for Grant BD 1275/95
PY - 2000
Y1 - 2000
N2 - The kinetics of the reaction of NO with activated carbon without catalyst and impregnated Barium was investigated. The conversion of NO was studied up to 900°C using a fixed bed reactor whose effluents were analysed using a GC/MS on line. Based on the in situ XRD results, Barium catalysed NO reduction mechanism was proposed and adjust to isothermal kinetic results obtained at 400°C and 700°C. Also a mechanism was proposed to the uncatalysed reaction and adjusted to isothermal kinetic results obtained at the same temperatures.
AB - The kinetics of the reaction of NO with activated carbon without catalyst and impregnated Barium was investigated. The conversion of NO was studied up to 900°C using a fixed bed reactor whose effluents were analysed using a GC/MS on line. Based on the in situ XRD results, Barium catalysed NO reduction mechanism was proposed and adjust to isothermal kinetic results obtained at 400°C and 700°C. Also a mechanism was proposed to the uncatalysed reaction and adjusted to isothermal kinetic results obtained at the same temperatures.
UR - http://www.scopus.com/inward/record.url?scp=0034388491&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0034388491
SN - 0167-2991
VL - 130 B
SP - 1421
EP - 1426
JO - Studies in Surface Science and Catalysis
JF - Studies in Surface Science and Catalysis
ER -