Microwave accelerated facile synthesis of fused polynuclear hydrocarbons in dry media by intramolecular Friedel-Crafts alkylation

Vanya B. Kurteva; António Gil Santos; Carlos A.M. Afonso

doi:10.1039/b311750m

Microwave accelerated facile synthesis of fused polynuclear hydrocarbons in dry media by intramolecular Friedel-Crafts alkylation

Vanya B. Kurteva, António Gil Santos, Carlos A.M. Afonso

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19 Citations (Scopus)

Abstract

Fused polynuclear tetrahydro arenes are synthesised in a fast, simple, high yielding and regiospecific procedure by an intramolecular Friedel-Crafts alkylation in dry media under microwave irradiation of the corresponding 1-bromo-4-arylbutanes immobilised on silica. The observed reactivity is rationalised by molecular modelling studies which suggest the occurence of a concerted mechanism.

Original language	English
Pages (from-to)	514-523
Number of pages	10
Journal	Organic & Biomolecular Chemistry
Volume	2
Issue number	4
DOIs	https://doi.org/10.1039/b311750m
Publication status	Published - 21 Feb 2004

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AB - Fused polynuclear tetrahydro arenes are synthesised in a fast, simple, high yielding and regiospecific procedure by an intramolecular Friedel-Crafts alkylation in dry media under microwave irradiation of the corresponding 1-bromo-4-arylbutanes immobilised on silica. The observed reactivity is rationalised by molecular modelling studies which suggest the occurence of a concerted mechanism.

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Microwave accelerated facile synthesis of fused polynuclear hydrocarbons in dry media by intramolecular Friedel-Crafts alkylation

Abstract

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