Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)

Inma Angurell, João C. Lima, Laura I. Rodríguez, Laura Rodriguez, Oriol Rossell, Miquel Seco

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The reaction of [Re(bipy)(CO)3(C≡Cpy)] with two carbosilane dendrimers containing terminal (p-cymene)Ru(triflate)2 units gives bimetallic dendrimers functionalised with (p-cymene)Ru(triflate) (pyC≡C)Re(bipy)(CO)3 units. Dendrimers of this kind can be envisaged as formed by two metal layers: the internal, constituted by ruthenium atoms, and the external, by rhenium metals. The luminescent properties of these species are only attributed to the rhenium moieties.

Original languageEnglish
Pages (from-to)1004-1008
Number of pages5
JournalNew Journal of Chemistry
Volume30
Issue number7
DOIs
Publication statusPublished - 12 Jul 2006

Keywords

  • Dendrimers
  • Phosphorus
  • Phosphorus dendrimers

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