Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)

Inma Angurell; João C. Lima; Laura I. Rodríguez; Laura Rodriguez; Oriol Rossell; Miquel Seco

doi:10.1039/b518356a

Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)

Inma Angurell, João C. Lima, Laura I. Rodríguez, Laura Rodriguez, Oriol Rossell, Miquel Seco

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The reaction of [Re(bipy)(CO)₃(C≡Cpy)] with two carbosilane dendrimers containing terminal (p-cymene)Ru(triflate)₂ units gives bimetallic dendrimers functionalised with (p-cymene)Ru(triflate) (pyC≡C)Re(bipy)(CO)₃ units. Dendrimers of this kind can be envisaged as formed by two metal layers: the internal, constituted by ruthenium atoms, and the external, by rhenium metals. The luminescent properties of these species are only attributed to the rhenium moieties.

Original language	English
Pages (from-to)	1004-1008
Number of pages	5
Journal	New Journal of Chemistry
Volume	30
Issue number	7
DOIs	https://doi.org/10.1039/b518356a
Publication status	Published - 12 Jul 2006

Keywords

Dendrimers
Phosphorus
Phosphorus dendrimers

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10.1039/b518356a

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title = "Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)",

abstract = "The reaction of [Re(bipy)(CO)3(C≡Cpy)] with two carbosilane dendrimers containing terminal (p-cymene)Ru(triflate)2 units gives bimetallic dendrimers functionalised with (p-cymene)Ru(triflate) (pyC≡C)Re(bipy)(CO)3 units. Dendrimers of this kind can be envisaged as formed by two metal layers: the internal, constituted by ruthenium atoms, and the external, by rhenium metals. The luminescent properties of these species are only attributed to the rhenium moieties.",

keywords = "Dendrimers, Phosphorus, Phosphorus dendrimers",

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AU - Angurell, Inma

AU - Lima, João C.

AU - Rodríguez, Laura I.

AU - Rodriguez, Laura

AU - Rossell, Oriol

AU - Seco, Miquel

PY - 2006/7/12

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N2 - The reaction of [Re(bipy)(CO)3(C≡Cpy)] with two carbosilane dendrimers containing terminal (p-cymene)Ru(triflate)2 units gives bimetallic dendrimers functionalised with (p-cymene)Ru(triflate) (pyC≡C)Re(bipy)(CO)3 units. Dendrimers of this kind can be envisaged as formed by two metal layers: the internal, constituted by ruthenium atoms, and the external, by rhenium metals. The luminescent properties of these species are only attributed to the rhenium moieties.

AB - The reaction of [Re(bipy)(CO)3(C≡Cpy)] with two carbosilane dendrimers containing terminal (p-cymene)Ru(triflate)2 units gives bimetallic dendrimers functionalised with (p-cymene)Ru(triflate) (pyC≡C)Re(bipy)(CO)3 units. Dendrimers of this kind can be envisaged as formed by two metal layers: the internal, constituted by ruthenium atoms, and the external, by rhenium metals. The luminescent properties of these species are only attributed to the rhenium moieties.

KW - Dendrimers

KW - Phosphorus

KW - Phosphorus dendrimers

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JF - New Journal of Chemistry

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IS - 7

ER -

Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)

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