TY - JOUR
T1 - Melting behaviour of ionic salts in the presence of high pressure CO2
AU - Serbanovic, Ana
AU - Petrovski, Željko
AU - Manic, Marina
AU - Marques, Carolina S.
AU - Carrera, Gonçalo V. S. M.
AU - Branco, Luis C.
AU - Afonso, Carlos A. M.
AU - Nunes da Ponte, Manuel
N1 - info:eu-repo/grantAgreement/FCT/3599-PPCDT/70383/PT#
info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F35004%2F2007/PT#
info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F38343%2F2007/PT#
PY - 2010/7/15
Y1 - 2010/7/15
N2 - In this article, we present experimental data on high pressure CO2-induced melting point depression of low-melting ionic salts (ionic liquids). A phenomenon that is widely reported for other organic compounds (e.g. polymers and lipids), it has only received more attention for ionic liquids in the last couple of years, and since a dramatic effect of 120K melting point depression was discovered. The obtained results are compared with recently published data, in order to rationalize the effect of high pressure CO2 on melting of ionic liquid-like salts.
AB - In this article, we present experimental data on high pressure CO2-induced melting point depression of low-melting ionic salts (ionic liquids). A phenomenon that is widely reported for other organic compounds (e.g. polymers and lipids), it has only received more attention for ionic liquids in the last couple of years, and since a dramatic effect of 120K melting point depression was discovered. The obtained results are compared with recently published data, in order to rationalize the effect of high pressure CO2 on melting of ionic liquid-like salts.
KW - Ionic liquids
KW - Melting point depression
KW - Phase behaviour
KW - Solubility
UR - http://www.scopus.com/inward/record.url?scp=77956877964&partnerID=8YFLogxK
U2 - 10.1016/j.fluid.2010.03.015
DO - 10.1016/j.fluid.2010.03.015
M3 - Article
AN - SCOPUS:77956877964
SN - 0378-3812
VL - 294
SP - 121
EP - 130
JO - Fluid Phase Equilibria
JF - Fluid Phase Equilibria
IS - 1-2(SI)
ER -