Manganese(II), cobalt(II), and nickel(II) perchlorate complexes containing N,O donor macrocyclic ligands

Carlos Lodeiro, Jose Luis Capelo, Emilia Bértolo, Rufina Bastida

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

Mononuclear macrocyclic complexes of manganese(II), cobalt(II) and nickel(II) perchlorate using 10 different oxaazamacrocyclic ligands (L 1 -L 10 ) have been prepared and characterized. The complexation reactions with the diiminic ligands were obtained by template condensation of the appropriate dialdehyde and diamine precursors; the reduced macrocycle complexes were synthesized using a direct route. The complexes have been characterized by elemental analyses, molar conductivity, mass spectrometry, IR, UV-vis spectroscopy, diffuse reflectance and magnetic susceptibility measurements.

Original languageEnglish
Pages (from-to)1110-1115
Number of pages6
JournalZeitschrift Fur Anorganische Und Allgemeine Chemie
Volume630
Issue number7
DOIs
Publication statusPublished - 7 Oct 2004

Keywords

  • Cobalt
  • Manganese
  • Nickel
  • Oxaaza macrocycles
  • Schiff-bases

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