@article{eee5f71ef76446819df6ca55e963d159,
title = "Manganese-catalyzed Synthesis of Imines from Primary Alcohols and Aromatic Amines",
abstract = "Herein, we describe the synthesis of a wide variety of imines through oxidative coupling of alcohols and aromatic amines catalyzed by Mn complexes bearing N^N triazole ligands. A wide variety of imines in excellent yields (up to 99%) have been prepared. Mn-based catalysts proved to be highly efficient and versatile, allowing for the first time the preparation of several imines containing N-based heterocycles. ",
author = "Daniel Raydan and Sofia Fri{\~a}es and Nuno Viduedo and Santos, {Ana Sofia} and Clara Gomes and Beatriz Royo and Marques, {Maria M. B.}",
note = "The authors thank the Funda{\c c}{\~a}o para a Ci{\^e}ncia e Tecnologia (FCT, PTDC/QUI-QOR/0712/2020 and PTDC/QUI-QIN/0359/2021, and fellowships PD/BD/142876/2018 (A.S.S.) PD/BD/05960/2020 (D.R.), and SFRH/BD/131955/2017 (S.F.). The authors also thank the support by the Laborat{\'o}rio Associado para a Qu{\'i}mica Verde (LAQV), which is financed by national funds from FCT/Minist{\'e}rio da Ci{\^e}ncia, Tecnologia e Ensino Superior (FCT/MCTES, UIDB/50006/2020, UIDP/50006/2020, and LA/P/0008/2020), UCIBIO (UID/UIDB/04378/2020 and UID/UIDP/04378/2020), i4HB (LA/P/0140/2020) and MOSTMICRO-ITQB (UIDB/04612/2020). The National NMR Facility is supported by FCT, ROTEIRO/0031/2013–PINFRA/22161/2016, co-financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC) and CERMAX (022162). We thank C. Almeida for elemental analysis at ITQB laboratories, and XTAL – Macromolecular Crystallography group (UCIBIO and i4HB) for granting access to the X-ray diffractometer. X-ray infrastructure financed by FCT/Minist{\'e}rio da Ci{\^e}ncia, Tecnologia e Ensino Superior (FCT/MCTES, RECI/BBB-BEP/0124/2012).",
year = "2022",
doi = "10.1055/a-1828-1678",
language = "English",
volume = "33",
pages = "1290--1294",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "13",
}