TY - JOUR
T1 - Low-energy electron interactions with dimethyl disulphide
AU - Matias, C.
AU - Mauracher, A.
AU - Scheier, P.
AU - Limão-Vieira, P.
AU - Denifl, S.
N1 - This work has been supported by the Fonds zur Forderung der wissenschaftlichen Forschung (FWF Project No. P22665), Wien, the European Commission, Brussels, via COST Action MP1002 programme Nanoscale Insights into Ion Beam Cancer Therapy (Nano-IBCT), the Austrian Ministry of Science BMWF as part of the Konjunkturpaket II and as part of the UniInfrastrukturprogramm of the Focal Point Scientific Computing at the University of Innsbruck. A.M. acknowledges a Grant from the Nachwuchsforderung of the University of Innsbruck. PL-V acknowledges partial funding from the research Grants PEst-OE/FIS/UI0068/2014 and PTDC/FIS/ATO/1832/2012.
PY - 2014/6/17
Y1 - 2014/6/17
N2 - Electron attachment experiments have been performed with dimethyl disulphide, C2H6S2, in the gas phase by means of a crossed electron-molecular beam experiment. Ion yields for 8 anions have been measured in the energy range from ∼0 to 15 eV. Many of the dissociative electron attachment products observed at low energy arise from surprisingly complex reactions associated with multiple bond cleavages as well as structural and electronic rearrangement. Quantum chemical calculations on the electronic properties of C2H6S2 have been performed in order to complement the experimental investigations.
AB - Electron attachment experiments have been performed with dimethyl disulphide, C2H6S2, in the gas phase by means of a crossed electron-molecular beam experiment. Ion yields for 8 anions have been measured in the energy range from ∼0 to 15 eV. Many of the dissociative electron attachment products observed at low energy arise from surprisingly complex reactions associated with multiple bond cleavages as well as structural and electronic rearrangement. Quantum chemical calculations on the electronic properties of C2H6S2 have been performed in order to complement the experimental investigations.
UR - http://www.scopus.com/inward/record.url?scp=84901840092&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2014.05.016
DO - 10.1016/j.cplett.2014.05.016
M3 - Article
AN - SCOPUS:84901840092
VL - 605-606
SP - 71
EP - 76
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
ER -