Low energy electron interaction with free and bound SF5CF3: Negative ion formation from single molecules, clusters and nanofilms

Richard Balog; Michal Stano; Paulo Manuel Assis Loureiro Limão-vieira; Constanze König; Ilko Bald; Nigel J. Mason; Eugen Illenberger

doi:10.1063/1.1617978

Low energy electron interaction with free and bound SF5CF3: Negative ion formation from single molecules, clusters and nanofilms

Richard Balog, Michal Stano, Paulo Manuel Assis Loureiro Limão-vieira, Constanze König, Ilko Bald, Nigel J. Mason, Eugen Illenberger

DF – Departamento de Física

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Low energy electron induced reactions in free and bound SF5CF3 induced by low energy electrons in the energy range 0-18 eV were studied. The experiments include negative ion formation from gas phase molecules under single collision conditions, from molecular aggregates in a supersonic beam and electron stimulated desorption (ESD) of negative ions from SF5CF3 nanofilms and from submonolayers of SF5CF3 adsorbed on the surface of solid Xe and amorphous water ice. Overall, information on how the intrinsic reactivity of the compound towards low energy electrons is affected by its real environment was obtained.

Original language	English
Pages (from-to)	10396-10403
Number of pages	8
Journal	Journal of Chemical Physics
Volume	119
Issue number	19
DOIs	https://doi.org/10.1063/1.1617978
Publication status	Published - 1 Jan 2003

Keywords

Transmission electron microscopy
Chemical bonds
Desorption
Dissociation
Electron energy loss spectroscopy
Electron resonance
Electronic density of states
Electrons
Molecular dynamics
Photochemical reactions
Photoelectron spectroscopy

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10.1063/1.1617978

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title = "Low energy electron interaction with free and bound SF5CF3: Negative ion formation from single molecules, clusters and nanofilms",

abstract = "Low energy electron induced reactions in free and bound SF5CF3 induced by low energy electrons in the energy range 0-18 eV were studied. The experiments include negative ion formation from gas phase molecules under single collision conditions, from molecular aggregates in a supersonic beam and electron stimulated desorption (ESD) of negative ions from SF5CF3 nanofilms and from submonolayers of SF5CF3 adsorbed on the surface of solid Xe and amorphous water ice. Overall, information on how the intrinsic reactivity of the compound towards low energy electrons is affected by its real environment was obtained.",

keywords = "Transmission electron microscopy, Chemical bonds, Desorption, Dissociation, Electron energy loss spectroscopy, Electron resonance, Electronic density of states, Electrons, Molecular dynamics, Photochemical reactions, Photoelectron spectroscopy",

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Low energy electron interaction with free and bound SF5CF3: Negative ion formation from single molecules, clusters and nanofilms. / Balog, Richard; Stano, Michal; Limão-vieira, Paulo Manuel Assis Loureiro; König, Constanze; Bald, Ilko; Mason, Nigel J.; Illenberger, Eugen.

In: Journal of Chemical Physics, Vol. 119, No. 19, 01.01.2003, p. 10396-10403.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Low energy electron interaction with free and bound SF5CF3: Negative ion formation from single molecules, clusters and nanofilms

AU - Balog, Richard

AU - Stano, Michal

AU - Limão-vieira, Paulo Manuel Assis Loureiro

AU - König, Constanze

AU - Bald, Ilko

AU - Mason, Nigel J.

AU - Illenberger, Eugen

PY - 2003/1/1

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N2 - Low energy electron induced reactions in free and bound SF5CF3 induced by low energy electrons in the energy range 0-18 eV were studied. The experiments include negative ion formation from gas phase molecules under single collision conditions, from molecular aggregates in a supersonic beam and electron stimulated desorption (ESD) of negative ions from SF5CF3 nanofilms and from submonolayers of SF5CF3 adsorbed on the surface of solid Xe and amorphous water ice. Overall, information on how the intrinsic reactivity of the compound towards low energy electrons is affected by its real environment was obtained.

AB - Low energy electron induced reactions in free and bound SF5CF3 induced by low energy electrons in the energy range 0-18 eV were studied. The experiments include negative ion formation from gas phase molecules under single collision conditions, from molecular aggregates in a supersonic beam and electron stimulated desorption (ESD) of negative ions from SF5CF3 nanofilms and from submonolayers of SF5CF3 adsorbed on the surface of solid Xe and amorphous water ice. Overall, information on how the intrinsic reactivity of the compound towards low energy electrons is affected by its real environment was obtained.

KW - Transmission electron microscopy

KW - Chemical bonds

KW - Desorption

KW - Dissociation

KW - Electron energy loss spectroscopy

KW - Electron resonance

KW - Electronic density of states

KW - Electrons

KW - Molecular dynamics

KW - Photochemical reactions

KW - Photoelectron spectroscopy

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U2 - 10.1063/1.1617978

DO - 10.1063/1.1617978

M3 - Article

VL - 119

SP - 10396

EP - 10403

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 19

ER -

Low energy electron interaction with free and bound SF5CF3: Negative ion formation from single molecules, clusters and nanofilms

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Keywords

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