Low energy electron interaction with free and bound SF5CF3: Negative ion formation from single molecules, clusters and nanofilms

Richard Balog, Michal Stano, Paulo Manuel Assis Loureiro Limão-vieira, Constanze König, Ilko Bald, Nigel J. Mason, Eugen Illenberger

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Low energy electron induced reactions in free and bound SF5CF3 induced by low energy electrons in the energy range 0-18 eV were studied. The experiments include negative ion formation from gas phase molecules under single collision conditions, from molecular aggregates in a supersonic beam and electron stimulated desorption (ESD) of negative ions from SF5CF3 nanofilms and from submonolayers of SF5CF3 adsorbed on the surface of solid Xe and amorphous water ice. Overall, information on how the intrinsic reactivity of the compound towards low energy electrons is affected by its real environment was obtained.
Original languageEnglish
Pages (from-to)10396-10403
Number of pages8
JournalJournal of Chemical Physics
Volume119
Issue number19
DOIs
Publication statusPublished - 1 Jan 2003

Keywords

  • Transmission electron microscopy
  • Chemical bonds
  • Desorption
  • Dissociation
  • Electron energy loss spectroscopy
  • Electron resonance
  • Electronic density of states
  • Electrons
  • Molecular dynamics
  • Photochemical reactions
  • Photoelectron spectroscopy

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