Isomerization of α-pinene over Ti02: Kinetics and catalyst optimization

A. Severino; J. Vital; L. S. Lobo

doi:10.1016/S0167-2991(08)63383-2

Isomerization of α-pinene over Ti02: Kinetics and catalyst optimization

A. Severino, J. Vital, L. S. Lobo

DQ - Departamento de Química

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

α-Pinene gives a good yield of camphene over Ti0₂ catalysts. The optimization of selectivity and yield depends on the level of acidity, activation time, activation temperature and other factors. Modelling of the kinetic system is performed by lumping species and using Langmuir-Hinshelwood kinetics. XRD shows that Ti0₂ is present as anatase and IR shows that acidity is mostly of the Bronsted type. The specific surface of ca. 400 m²/g is mostly due to micropores. The average pore radius is 20 Å. This may have an effect on selectivity.

Original language	English
Pages (from-to)	685-692
Number of pages	8
Journal	Studies in Surface Science and Catalysis
Volume	78
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)63383-2
Publication status	Published - 1 Jan 1993

Access to Document

10.1016/S0167-2991(08)63383-2Licence: CC BY-NC-ND

Cite this

@article{485f81894b1f4687ae9ce70b6fc0a59b,

title = "Isomerization of α-pinene over Ti02: Kinetics and catalyst optimization",

abstract = "α-Pinene gives a good yield of camphene over Ti02 catalysts. The optimization of selectivity and yield depends on the level of acidity, activation time, activation temperature and other factors. Modelling of the kinetic system is performed by lumping species and using Langmuir-Hinshelwood kinetics. XRD shows that Ti02 is present as anatase and IR shows that acidity is mostly of the Bronsted type. The specific surface of ca. 400 m2/g is mostly due to micropores. The average pore radius is 20 {\AA}. This may have an effect on selectivity.",

author = "A. Severino and J. Vital and Lobo, {L. S.}",

year = "1993",

month = jan,

day = "1",

doi = "10.1016/S0167-2991(08)63383-2",

language = "English",

volume = "78",

pages = "685--692",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier BV",

number = "C",

}

TY - JOUR

T1 - Isomerization of α-pinene over Ti02: Kinetics and catalyst optimization

AU - Severino, A.

AU - Vital, J.

AU - Lobo, L. S.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - α-Pinene gives a good yield of camphene over Ti02 catalysts. The optimization of selectivity and yield depends on the level of acidity, activation time, activation temperature and other factors. Modelling of the kinetic system is performed by lumping species and using Langmuir-Hinshelwood kinetics. XRD shows that Ti02 is present as anatase and IR shows that acidity is mostly of the Bronsted type. The specific surface of ca. 400 m2/g is mostly due to micropores. The average pore radius is 20 Å. This may have an effect on selectivity.

AB - α-Pinene gives a good yield of camphene over Ti02 catalysts. The optimization of selectivity and yield depends on the level of acidity, activation time, activation temperature and other factors. Modelling of the kinetic system is performed by lumping species and using Langmuir-Hinshelwood kinetics. XRD shows that Ti02 is present as anatase and IR shows that acidity is mostly of the Bronsted type. The specific surface of ca. 400 m2/g is mostly due to micropores. The average pore radius is 20 Å. This may have an effect on selectivity.

UR - http://www.scopus.com/inward/record.url?scp=0042577531&partnerID=8YFLogxK

U2 - 10.1016/S0167-2991(08)63383-2

DO - 10.1016/S0167-2991(08)63383-2

M3 - Article

AN - SCOPUS:0042577531

VL - 78

SP - 685

EP - 692

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

SN - 0167-2991

IS - C

ER -

Isomerization of α-pinene over Ti02: Kinetics and catalyst optimization

Abstract

Access to Document

Other files and links

Fingerprint

Cite this