Iron oxide-supported copper oxide nanoparticles (nanocat-Fe-CuO): Magnetically recyclable catalysts for the synthesis of pyrazole derivatives, 4-methoxyaniline, and ullmann-type condensation reactions

Sharad N. Shelke; Swapnil R. Bankar; Ganesh R. Mhaske; Samadhan S. Kadam; Dinesh K. Murade; Shashikant B. Bhorkade; Anuj K. Rathi; Nenad Bundaleski; Orlando M N D Teodoro; Radek Zboril; Rajender S. Varma; Manoj B. Gawande

doi:10.1021/sc500160f

Iron oxide-supported copper oxide nanoparticles (nanocat-Fe-CuO): Magnetically recyclable catalysts for the synthesis of pyrazole derivatives, 4-methoxyaniline, and ullmann-type condensation reactions

Sharad N. Shelke, Swapnil R. Bankar, Ganesh R. Mhaske, Samadhan S. Kadam, Dinesh K. Murade, Shashikant B. Bhorkade, Anuj K. Rathi, Nenad Bundaleski, Orlando M N D Teodoro, Radek Zboril, Rajender S. Varma, Manoj B. Gawande

Research output: Contribution to journal › Article › peer-review

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Abstract

An efficient and benign protocol is reported for the synthesis of medicinally important pyrazole derivatives, 4-methoxyaniline, and Ullmann-type condensation reaction using magnetically separable and reusable magnetite-supported copper (nanocat-Fe-CuO) nanoparticles under mild conditions. Nanoparticles with average size of 20-30 nm have been synthesized using simple impregnation techniques in aqueous medium from readily available inexpensive starting materials and were recycled six times without loss in catalytic activity.

Original language	English
Pages (from-to)	1699-1706
Number of pages	8
Journal	ACS Sustainable Chemistry & Engineering
Volume	2
Issue number	7
DOIs	https://doi.org/10.1021/sc500160f
Publication status	Published - 7 Jul 2014

Keywords

Benign media
Magnetite-copper oxide
Pyrazole synthesis
Recyclable catalysts
Ullmann reaction

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/sc500160fLicence: CC BY-NC

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Shelke, S. N., Bankar, S. R., Mhaske, G. R., Kadam, S. S., Murade, D. K., Bhorkade, S. B., Rathi, A. K., Bundaleski, N., Teodoro, O. M. N. D., Zboril, R., Varma, R. S., & Gawande, M. B. (2014). Iron oxide-supported copper oxide nanoparticles (nanocat-Fe-CuO): Magnetically recyclable catalysts for the synthesis of pyrazole derivatives, 4-methoxyaniline, and ullmann-type condensation reactions. ACS Sustainable Chemistry & Engineering, 2(7), 1699-1706. https://doi.org/10.1021/sc500160f

@article{6a696004a17c4edf82a8b52c25c2da66,

title = "Iron oxide-supported copper oxide nanoparticles (nanocat-Fe-CuO): Magnetically recyclable catalysts for the synthesis of pyrazole derivatives, 4-methoxyaniline, and ullmann-type condensation reactions",

abstract = "An efficient and benign protocol is reported for the synthesis of medicinally important pyrazole derivatives, 4-methoxyaniline, and Ullmann-type condensation reaction using magnetically separable and reusable magnetite-supported copper (nanocat-Fe-CuO) nanoparticles under mild conditions. Nanoparticles with average size of 20-30 nm have been synthesized using simple impregnation techniques in aqueous medium from readily available inexpensive starting materials and were recycled six times without loss in catalytic activity.",

keywords = "Benign media, Magnetite-copper oxide, Pyrazole synthesis, Recyclable catalysts, Ullmann reaction",

author = "Shelke, {Sharad N.} and Bankar, {Swapnil R.} and Mhaske, {Ganesh R.} and Kadam, {Samadhan S.} and Murade, {Dinesh K.} and Bhorkade, {Shashikant B.} and Rathi, {Anuj K.} and Nenad Bundaleski and Teodoro, {Orlando M N D} and Radek Zboril and Varma, {Rajender S.} and Gawande, {Manoj B.}",

note = "The authors are thankful to the Director of SAW, Panjab University (Chandigarh, India), for the spectral analysis. We are also grateful to the Principal Dr. K. H. Shinde and Dr. A. B. Nikumbh (HOD), S.S.G.M. College, Kopargaon, Ahmednagar (MH), for providing research facilities and constant encouragement. The authors gratefully acknowledge support by the Operational Program Research and Development for Innovations European Regional Development Fund (project CZ.1.05/2.1.00/03.0058) and by the Operational Program Education for competitiveness European Social Fund (project CZ.1.07/2.3.00/30.0041) of the Ministry of Education, Youth and Sports of the Czech Republic as well as by the Portuguese Research Grant Pest-OE/FIS/UI0068/2011 through FCT-MEC.",

year = "2014",

month = jul,

day = "7",

doi = "10.1021/sc500160f",

language = "English",

volume = "2",

pages = "1699--1706",

journal = "ACS Sustainable Chemistry & Engineering",

issn = "2168-0485",

publisher = "ACS - American Chemical Society",

number = "7",

}

Shelke, SN, Bankar, SR, Mhaske, GR, Kadam, SS, Murade, DK, Bhorkade, SB, Rathi, AK, Bundaleski, N , Teodoro, OMND, Zboril, R, Varma, RS & Gawande, MB 2014, 'Iron oxide-supported copper oxide nanoparticles (nanocat-Fe-CuO): Magnetically recyclable catalysts for the synthesis of pyrazole derivatives, 4-methoxyaniline, and ullmann-type condensation reactions', ACS Sustainable Chemistry & Engineering, vol. 2, no. 7, pp. 1699-1706. https://doi.org/10.1021/sc500160f

Iron oxide-supported copper oxide nanoparticles (nanocat-Fe-CuO): Magnetically recyclable catalysts for the synthesis of pyrazole derivatives, 4-methoxyaniline, and ullmann-type condensation reactions. / Shelke, Sharad N.; Bankar, Swapnil R.; Mhaske, Ganesh R. et al.
In: ACS Sustainable Chemistry & Engineering, Vol. 2, No. 7, 07.07.2014, p. 1699-1706.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Iron oxide-supported copper oxide nanoparticles (nanocat-Fe-CuO)

T2 - Magnetically recyclable catalysts for the synthesis of pyrazole derivatives, 4-methoxyaniline, and ullmann-type condensation reactions

AU - Shelke, Sharad N.

AU - Bankar, Swapnil R.

AU - Mhaske, Ganesh R.

AU - Kadam, Samadhan S.

AU - Murade, Dinesh K.

AU - Bhorkade, Shashikant B.

AU - Rathi, Anuj K.

AU - Bundaleski, Nenad

AU - Teodoro, Orlando M N D

AU - Zboril, Radek

AU - Varma, Rajender S.

AU - Gawande, Manoj B.

N1 - The authors are thankful to the Director of SAW, Panjab University (Chandigarh, India), for the spectral analysis. We are also grateful to the Principal Dr. K. H. Shinde and Dr. A. B. Nikumbh (HOD), S.S.G.M. College, Kopargaon, Ahmednagar (MH), for providing research facilities and constant encouragement. The authors gratefully acknowledge support by the Operational Program Research and Development for Innovations European Regional Development Fund (project CZ.1.05/2.1.00/03.0058) and by the Operational Program Education for competitiveness European Social Fund (project CZ.1.07/2.3.00/30.0041) of the Ministry of Education, Youth and Sports of the Czech Republic as well as by the Portuguese Research Grant Pest-OE/FIS/UI0068/2011 through FCT-MEC.

PY - 2014/7/7

Y1 - 2014/7/7

N2 - An efficient and benign protocol is reported for the synthesis of medicinally important pyrazole derivatives, 4-methoxyaniline, and Ullmann-type condensation reaction using magnetically separable and reusable magnetite-supported copper (nanocat-Fe-CuO) nanoparticles under mild conditions. Nanoparticles with average size of 20-30 nm have been synthesized using simple impregnation techniques in aqueous medium from readily available inexpensive starting materials and were recycled six times without loss in catalytic activity.

AB - An efficient and benign protocol is reported for the synthesis of medicinally important pyrazole derivatives, 4-methoxyaniline, and Ullmann-type condensation reaction using magnetically separable and reusable magnetite-supported copper (nanocat-Fe-CuO) nanoparticles under mild conditions. Nanoparticles with average size of 20-30 nm have been synthesized using simple impregnation techniques in aqueous medium from readily available inexpensive starting materials and were recycled six times without loss in catalytic activity.

KW - Benign media

KW - Magnetite-copper oxide

KW - Pyrazole synthesis

KW - Recyclable catalysts

KW - Ullmann reaction

UR - http://www.scopus.com/inward/record.url?scp=84903945185&partnerID=8YFLogxK

U2 - 10.1021/sc500160f

DO - 10.1021/sc500160f

M3 - Article

AN - SCOPUS:84903945185

SN - 2168-0485

VL - 2

SP - 1699

EP - 1706

JO - ACS Sustainable Chemistry & Engineering

JF - ACS Sustainable Chemistry & Engineering

IS - 7

ER -

Iron oxide-supported copper oxide nanoparticles (nanocat-Fe-CuO): Magnetically recyclable catalysts for the synthesis of pyrazole derivatives, 4-methoxyaniline, and ullmann-type condensation reactions

Abstract

Keywords

UN SDGs

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