Ionic liquid-based materials: A platform to design engineered CO₂ separation membranes

During the past decade, significant advances in ionic liquid-based materials for the development of CO₂ separation membranes have been accomplished. This review presents a perspective on different strategies that use ionic liquid-based materials as a unique tuneable platform to design task-specific advanced materials for CO₂ separation membranes. Based on compilation and analysis of the data hitherto reported, we provide a judicious assessment of the CO₂ separation efficiency of different membranes, and highlight breakthroughs and key challenges in this field. In particular, configurations such as supported ionic liquid membranes, polymer/ionic liquid composite membranes, gelled ionic liquid membranes and poly(ionic liquid)-based membranes are detailed, discussed and evaluated in terms of their efficiency, which is attributed to their chemical and structural features. Finally, an integrated perspective on technology, economy and sustainability is provided.