Abstract
| Original language | Unknown |
|---|---|
| Pages (from-to) | 1007-1016 |
| Journal | Express Polymer Letters |
| Volume | 6 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 1 Jan 2012 |
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Investigation of polymer electrolytes based on agar and ionic liquids. / Esperanca, Jose Manuel.
In: Express Polymer Letters, Vol. 6, No. 12, 01.01.2012, p. 1007-1016.Research output: Contribution to journal › Article
TY - JOUR
T1 - Investigation of polymer electrolytes based on agar and ionic liquids
AU - Esperanca, Jose Manuel
PY - 2012/1/1
Y1 - 2012/1/1
N2 - The possibility to use natural polymer as ionic conducting matrix was investigated in this study. Samples of agar-based electrolytes with different ionic liquids were prepared and characterized by physical and chemical analyses. The ionic liquids used in this work were 1-ethyl-3-methylimidazolium ethylsulfate, [C(2)mim][C2SO4], 1-ethyl-3-methylimidazolium acetate, [C(2)mim][OAc] and trimethyl-ethanolammonium acetate, [Ch][OAc].Samples of solvent-free electrolytes were prepared and characterized by ionic conductivity measurements, thermal analysis, electrochemical stability, X-ray diffraction, scanning electron microscopy and Fourier Transform infrared spectroscopy. Electrolyte samples are thermally stable up to approximately 190 degrees C. All the materials synthesized are semicrystalline. The electrochemical stability domain of all samples is about 2.0 V versus Li/Li+. The preliminary studies carried out with electrochromic devices (ECDs) incorporating optimized compositions have confirmed that these materials may perform as satisfactory multifunctional component layers in the field of 'smart windows', as well as ECD-based devices.
AB - The possibility to use natural polymer as ionic conducting matrix was investigated in this study. Samples of agar-based electrolytes with different ionic liquids were prepared and characterized by physical and chemical analyses. The ionic liquids used in this work were 1-ethyl-3-methylimidazolium ethylsulfate, [C(2)mim][C2SO4], 1-ethyl-3-methylimidazolium acetate, [C(2)mim][OAc] and trimethyl-ethanolammonium acetate, [Ch][OAc].Samples of solvent-free electrolytes were prepared and characterized by ionic conductivity measurements, thermal analysis, electrochemical stability, X-ray diffraction, scanning electron microscopy and Fourier Transform infrared spectroscopy. Electrolyte samples are thermally stable up to approximately 190 degrees C. All the materials synthesized are semicrystalline. The electrochemical stability domain of all samples is about 2.0 V versus Li/Li+. The preliminary studies carried out with electrochromic devices (ECDs) incorporating optimized compositions have confirmed that these materials may perform as satisfactory multifunctional component layers in the field of 'smart windows', as well as ECD-based devices.
KW - Agar matrix
KW - biodegradable polymers
KW - thermal properties
KW - smart polymer
U2 - 10.3144/expresspolymlett.2012.106
DO - 10.3144/expresspolymlett.2012.106
M3 - Article
VL - 6
SP - 1007
EP - 1016
JO - Express Polymer Letters
JF - Express Polymer Letters
SN - 1788-618X
IS - 12
ER -