Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators

E. L. Howard; H. Pourkheirollah; C. Pinheiro; C. A. T. Laia; A. J. Parola; M. Mäntysalo; D. Lupo

doi:10.1109/FLEPS57599.2023.10220370

Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators

E. L. Howard, H. Pourkheirollah, C. Pinheiro, C. A. T. Laia, A. J. Parola, M. Mäntysalo, D. Lupo

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Printed supercapacitors (SCs) are demonstrated to activate 1x 1 cm2 Irreversible Visual Indicators (IVIs) based on four different monomer systems: 3,4-Ethylenedioxythiophene (EDOT), bis-3,4-Ethylenedioxythiophene (BiEDOT), 2,2'- Bithiophene (Bithiophene), and 2,2':5',2'-Terthiophene (Terthiophene). The key parameters which determine whether the IVIs can be fully activated (A Optical Density > 0.9) are the activation potential, the coloration efficiency (CE) of the lVI's, and the initial voltage and charge density of the SCs. All four monomer systems can be fully activated by three of the printed SCs connected in series (3.55 V), but only BiEDOT and TerThiophene can be fully activated by two series connected printed SCs (2.35 V).

Original language	English
Title of host publication	FLEPS 2023
Subtitle of host publication	IEEE International Conference on Flexible and Printable Sensors and Systems
Place of Publication	New Jersey
Publisher	Institute of Electrical and Electronics Engineers (IEEE)
Number of pages	4
ISBN (Electronic)	978-1-6654-5733-0
ISBN (Print)	978-1-6654-9353-6
DOIs	https://doi.org/10.1109/FLEPS57599.2023.10220370
Publication status	Published - 2023
Event	5th IEEE International Conference on Flexible and Printable Sensors and Systems, FLEPS 2023 - Boston, United States Duration: 9 Jul 2023 → 12 Jul 2023

Publication series

Name	IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)
Publisher	Institute of Electrical and Electronics Engineers (IEEE)
ISSN (Print)	2832-8248
ISSN (Electronic)	2832-8256

Conference

Conference	5th IEEE International Conference on Flexible and Printable Sensors and Systems, FLEPS 2023
Country/Territory	United States
City	Boston
Period	9/07/23 → 12/07/23

Keywords

Circuit Integration
Electrochromic Displays
Electropolymerization
Irreversible Systems
Printed Electronics
Smart Labels
Supercapacitors

Access to Document

10.1109/FLEPS57599.2023.10220370

Cite this

Howard, E. L., Pourkheirollah, H., Pinheiro, C., Laia, C. A. T., Parola, A. J., Mäntysalo, M., & Lupo, D. (2023). Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators. In FLEPS 2023: IEEE International Conference on Flexible and Printable Sensors and Systems (IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)). Institute of Electrical and Electronics Engineers (IEEE). https://doi.org/10.1109/FLEPS57599.2023.10220370

Howard, E. L. ; Pourkheirollah, H. ; Pinheiro, C. et al. / Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators. FLEPS 2023: IEEE International Conference on Flexible and Printable Sensors and Systems. New Jersey : Institute of Electrical and Electronics Engineers (IEEE), 2023. (IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)).

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title = "Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators",

abstract = "Printed supercapacitors (SCs) are demonstrated to activate 1x 1 cm2 Irreversible Visual Indicators (IVIs) based on four different monomer systems: 3,4-Ethylenedioxythiophene (EDOT), bis-3,4-Ethylenedioxythiophene (BiEDOT), 2,2'- Bithiophene (Bithiophene), and 2,2':5',2'-Terthiophene (Terthiophene). The key parameters which determine whether the IVIs can be fully activated (A Optical Density > 0.9) are the activation potential, the coloration efficiency (CE) of the lVI's, and the initial voltage and charge density of the SCs. All four monomer systems can be fully activated by three of the printed SCs connected in series (3.55 V), but only BiEDOT and TerThiophene can be fully activated by two series connected printed SCs (2.35 V).",

keywords = "Circuit Integration, Electrochromic Displays, Electropolymerization, Irreversible Systems, Printed Electronics, Smart Labels, Supercapacitors",

author = "Howard, {E. L.} and H. Pourkheirollah and C. Pinheiro and Laia, {C. A. T.} and Parola, {A. J.} and M. M{\"a}ntysalo and D. Lupo",

note = "Funding Information: info:eu-repo/grantAgreement/EC/H2020/814299/EU# Publisher Copyright: {\textcopyright} 2023 IEEE.; 5th IEEE International Conference on Flexible and Printable Sensors and Systems, FLEPS 2023 ; Conference date: 09-07-2023 Through 12-07-2023",

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doi = "10.1109/FLEPS57599.2023.10220370",

language = "English",

isbn = "978-1-6654-9353-6",

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Howard, EL, Pourkheirollah, H, Pinheiro, C , Laia, CAT , Parola, AJ, Mäntysalo, M & Lupo, D 2023, Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators. in FLEPS 2023: IEEE International Conference on Flexible and Printable Sensors and Systems. IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS), Institute of Electrical and Electronics Engineers (IEEE), New Jersey, 5th IEEE International Conference on Flexible and Printable Sensors and Systems, FLEPS 2023, Boston, United States, 9/07/23. https://doi.org/10.1109/FLEPS57599.2023.10220370

Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators. / Howard, E. L.; Pourkheirollah, H.; Pinheiro, C. et al.
FLEPS 2023: IEEE International Conference on Flexible and Printable Sensors and Systems. New Jersey: Institute of Electrical and Electronics Engineers (IEEE), 2023. (IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators

AU - Howard, E. L.

AU - Pourkheirollah, H.

AU - Pinheiro, C.

AU - Laia, C. A. T.

AU - Parola, A. J.

AU - Mäntysalo, M.

AU - Lupo, D.

PY - 2023

Y1 - 2023

N2 - Printed supercapacitors (SCs) are demonstrated to activate 1x 1 cm2 Irreversible Visual Indicators (IVIs) based on four different monomer systems: 3,4-Ethylenedioxythiophene (EDOT), bis-3,4-Ethylenedioxythiophene (BiEDOT), 2,2'- Bithiophene (Bithiophene), and 2,2':5',2'-Terthiophene (Terthiophene). The key parameters which determine whether the IVIs can be fully activated (A Optical Density > 0.9) are the activation potential, the coloration efficiency (CE) of the lVI's, and the initial voltage and charge density of the SCs. All four monomer systems can be fully activated by three of the printed SCs connected in series (3.55 V), but only BiEDOT and TerThiophene can be fully activated by two series connected printed SCs (2.35 V).

AB - Printed supercapacitors (SCs) are demonstrated to activate 1x 1 cm2 Irreversible Visual Indicators (IVIs) based on four different monomer systems: 3,4-Ethylenedioxythiophene (EDOT), bis-3,4-Ethylenedioxythiophene (BiEDOT), 2,2'- Bithiophene (Bithiophene), and 2,2':5',2'-Terthiophene (Terthiophene). The key parameters which determine whether the IVIs can be fully activated (A Optical Density > 0.9) are the activation potential, the coloration efficiency (CE) of the lVI's, and the initial voltage and charge density of the SCs. All four monomer systems can be fully activated by three of the printed SCs connected in series (3.55 V), but only BiEDOT and TerThiophene can be fully activated by two series connected printed SCs (2.35 V).

KW - Circuit Integration

KW - Electrochromic Displays

KW - Electropolymerization

KW - Irreversible Systems

KW - Printed Electronics

KW - Smart Labels

KW - Supercapacitors

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U2 - 10.1109/FLEPS57599.2023.10220370

DO - 10.1109/FLEPS57599.2023.10220370

M3 - Conference contribution

AN - SCOPUS:85171588898

SN - 978-1-6654-9353-6

T3 - IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)

BT - FLEPS 2023

PB - Institute of Electrical and Electronics Engineers (IEEE)

CY - New Jersey

T2 - 5th IEEE International Conference on Flexible and Printable Sensors and Systems, FLEPS 2023

Y2 - 9 July 2023 through 12 July 2023

ER -

Howard EL, Pourkheirollah H, Pinheiro C , Laia CAT , Parola AJ, Mäntysalo M et al. Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators. In FLEPS 2023: IEEE International Conference on Flexible and Printable Sensors and Systems. New Jersey: Institute of Electrical and Electronics Engineers (IEEE). 2023. (IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)). doi: 10.1109/FLEPS57599.2023.10220370

Integration of Supercapacitors to Trigger In-Situ Electropolymerization for Irreversible Visual Indicators

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