Improved preparation of indenyl molybdenum(II) and tungsten(II) compounds

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Abstract

Oxidative addition of 1-bromo-1H-indene to [Mo(CO)(3)(NCMe)(3)] and [W(CO)(3)(NCEt)(3)] is a suitable method for preparation of the indenyl compounds [IndMo(CO)(3)Br] and [IndW(CO)(3)Br], respectively. These products were fully characterised using spectroscopic methods. Structure of [ IndW( CO) 3Br] was determined by single crystal X-ray diffraction analysis.
Original languageUnknown
Pages (from-to)1601-1603
JournalInorganica Chimica Acta
Volume363
Issue number7
DOIs
Publication statusPublished - 1 Jan 2010

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