The nickel tetrahedral sulfur-coordinated core formed upon metal replacement of the native iron in Desulfovibrio sp. rubredoxins is shown to mimic the reactivity pattern of nickel-containing hydrogenases with respect to hydrogen production, deuterium-proton exchange, and inhibition by carbon monoxide.
|Number of pages||3|
|Journal||Proceedings of the National Academy of Sciences of the United States of America|
|Publication status||Published - 1 Dec 1988|