Abstract
The nickel tetrahedral sulfur-coordinated core formed upon metal replacement of the native iron in Desulfovibrio sp. rubredoxins is shown to mimic the reactivity pattern of nickel-containing hydrogenases with respect to hydrogen production, deuterium-proton exchange, and inhibition by carbon monoxide.
| Original language | English |
|---|---|
| Pages (from-to) | 9378-9380 |
| Number of pages | 3 |
| Journal | Proceedings of the National Academy of Sciences of the United States of America |
| Volume | 85 |
| Issue number | 24 |
| Publication status | Published - 1 Dec 1988 |
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Saint-Martin, P., Lespinat, P. A., Fauque, G., Berlier, Y., LeGall, J., Moura, I., ... Moura, J. J. G. (1988). Hydrogen production and deuterium-proton exchange reactions catalyzed by Desulfovibrio nickel(II)-substituted rubredoxins. Proceedings of the National Academy of Sciences of the United States of America, 85(24), 9378-9380.