Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of epsilon-caprolactone

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Abstract

Zinc alkyl cations supported by N,N-BIAN-type bidentate ligands were found to be highly active in the immortal ROP of epsilon-caprolactone to yield narrowly disperse and chain length-controlled poly(epsilon-caprolactone), whether in solution or bulk polymerization conditions.
Original languageUnknown
Pages (from-to)3377-3379
JournalDalton Transactions
Volume41
Issue number12
DOIs
Publication statusPublished - 1 Jan 2012

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