Exploring the photocatalytic properties and the long-lifetime chemosensor ability of CI2[Ru(Bpy)2L] (L = 2,5,8,11,14-pentaaza[15])-2,2′-bipyridilophane)

C. Lodeiro; F. Pina; A.J. Parola; Andrea Bencini; Antonio Bianchi; Caria Bazzicalupi; S. Ciattini; Claudia Giorgi; A. Masotti; Barbara Valtancoli; J. Seixas de Melo

doi:10.1021/ic0105213

Exploring the photocatalytic properties and the long-lifetime chemosensor ability of CI2[Ru(Bpy)2L] (L = 2,5,8,11,14-pentaaza[15])-2,2′-bipyridilophane)

C. Lodeiro, F. Pina, A.J. Parola, Andrea Bencini, Antonio Bianchi, Caria Bazzicalupi, S. Ciattini, Claudia Giorgi, A. Masotti, Barbara Valtancoli, J. Seixas de Melo

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

In this work a new water-soluble long-lifetime chemosensor, containing a polyamine unit connected to a complexed Ru(II) metal center, is described. Its crystal structure has been characterized by X-ray analysis. The polyamine macrocyclic unit is capable of anchoring cationic or anionic substrates, according to its protonation state. Examples of electron transfer involving the ruthenium complex core and the bound substrate are presented. The photocatalytic ability of such a system is illustrated by the oxidation of iodide to iodine promoted by light absorption at 436 nm.

Original language	English
Pages (from-to)	6813-6819
Number of pages	7
Journal	Inorganic Chemistry
Volume	40
Issue number	26
DOIs	https://doi.org/10.1021/ic0105213
Publication status	Published - 17 Dec 2001

Keywords

metal complex
ruthenium derivative
article
catalysis
chemosensitivity
crystal structure
electron transport
photochemistry
sensor

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10.1021/ic0105213

https://www.scopus.com/inward/record.uri?eid=2-s2.0-20244366354&doi=10.1021%2fic0105213&partnerID=40&md5=fb8e99ef8385e9c452253e831c546179

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Lodeiro, C., Pina, F., Parola, A. J., Bencini, A., Bianchi, A., Bazzicalupi, C., Ciattini, S., Giorgi, C., Masotti, A., Valtancoli, B., & Seixas de Melo, J. (2001). Exploring the photocatalytic properties and the long-lifetime chemosensor ability of CI2[Ru(Bpy)2L] (L = 2,5,8,11,14-pentaaza[15])-2,2′-bipyridilophane). Inorganic Chemistry, 40(26), 6813-6819. https://doi.org/10.1021/ic0105213

@article{4609ad7162bf46d4bfee17105feac21d,

title = "Exploring the photocatalytic properties and the long-lifetime chemosensor ability of CI2[Ru(Bpy)2L] (L = 2,5,8,11,14-pentaaza[15])-2,2′-bipyridilophane)",

abstract = "In this work a new water-soluble long-lifetime chemosensor, containing a polyamine unit connected to a complexed Ru(II) metal center, is described. Its crystal structure has been characterized by X-ray analysis. The polyamine macrocyclic unit is capable of anchoring cationic or anionic substrates, according to its protonation state. Examples of electron transfer involving the ruthenium complex core and the bound substrate are presented. The photocatalytic ability of such a system is illustrated by the oxidation of iodide to iodine promoted by light absorption at 436 nm.",

keywords = "metal complex, ruthenium derivative, article, catalysis, chemosensitivity, crystal structure, electron transport, photochemistry, sensor",

author = "C. Lodeiro and F. Pina and A.J. Parola and Andrea Bencini and Antonio Bianchi and Caria Bazzicalupi and S. Ciattini and Claudia Giorgi and A. Masotti and Barbara Valtancoli and {Seixas de Melo}, J.",

note = "Cited By :21 Export Date: 7 May 2017 CODEN: INOCA Correspondence Address: Lodeiro, C.; Departamento de Qu{\'i}mica, Centro Quimica-Fina e Biotecnologia, Faculdade de Ciencias e Tecnologia, Quinta da Torre 2825, Monte de Caparica, Portugal; email: [email protected] References: Pina, F., Bernardo, M.A., Garci{\'a}-Espa{\~n}a, E., Eur. J. Inorg. Chem., p. 2143; Bazzicalupi, C., Bencini, A., Bianchi, A., Giorgi, C., Fusi, V., Valtancoli, B., Bernardo, M.A., Pina, F., Inorg. Chem., 38, p. 3806; Czarnik, A.W., Acc. Chem. Res., 27, p. 302; Czarnik, A.W., Fluorescent Chemosensors for Ion Molecule and Recognition, , American Chemical Society: Washington DC; Bissel, R.A., De Silva, A.P., Gunaratne, H.Q.N., Lynch, P.L.M., Maguaire, G.E.M., Sandanayake, K.R.A.S., Chem. Soc. Rev., p. 187; De Silva, A.P., Gunaratne, H.Q.N., Gunnlaugsson, T., Huxley, A.J.M., McCoy, C.P., Rademacher, J.T., Rice, T.E., Chem. Rev., 97, p. 1515; Lakowicz, J.R., Probe design and chemical sensing, , Topics in Fluorescence Spectroscopy 4; Plenum Press: New York; Murtaza, Z., Chang, Q., Rao, G., Lin, H., Lakowicz, J.R., Anal. Biochem., 247, p. 216; Grigg, R., Norbert, W.D.J.A., J. Chem. Soc. Chem. Commun., p. 1300; Kimura, E., Wada, S., Shionoya, M., Takahashi, T., Litaka, Y., J. Chem. Soc. Chem. Commun., p. 397; Rawle, S.C., Moore, P., Alcock, N.W., J. Chem. Soc., Chem. Commun., p. 684; Alcock, N.W., Clarke, A.J., Errington, W., Josceanu, A.M., Moore, P., Rawle, S.C., Sheldon, P., Turonek, M., Supramol. Chem., 6, p. 281. , and references therein; Szemes, F., Hesek, D., Chen, Z., Dent, S.W., Drew, M.G.B., Goulden, A.J., Graydon, A.R., Beer, P.D., Inorg. Chem., 35, p. 5868; Beer, P.D., Szemes, F., Balzani, V., Sala{\`a}, C.M., Drew, M.G.B., Dent, S.W., Maestri, M., J. Am. Chem. Soc., 119, p. 11864; Beer, P.D., Acc. Chem. Res., 31, p. 71; Beer, P.D., Gale, P.A., Angew. Chem., Int. Ed., 40, p. 486; Beer, P.D., Cadman, J., New J. Chem., 23, p. 347; Turro, C., Chang, C.K., Leroi, G.E., Cukier, R.I., Nocera, D.G., J. Am. Chem. Soc., 114, p. 4013; Roberts, J.A., Kirby, J.P., Nocera, D.G., J. Am. Chem. Soc., 117, p. 8051; Deng, Y., Roberts, J.A., Peng, S.M., Chang, C.K., Nocera, D.G., Angew. Chem., Int. Ed. Engl., 36, p. 2124; Kirby, J.P., Roberts, J.A., Nocera, D.G., J. Am. Chem. Soc., 119, p. 9230; Harriman, A., Magda, D.J., Sessler, J.L., J. Phys. Chem. B, 95, p. 1530; Harriman, A., Magda, D.J., Sessler, J.L., J. Chem. Soc., Chem. Commun., p. 345; Harriman, A., Kubo, Y., Sessler, J.L., J. Am. Chem. Soc., 114, p. 388; Harriman, A., Bing, W., Sessler, J.L., J. Am. Chem. Soc., 115, p. 10418; Harriman, A., Bing, W., Sessler, J.L., J. Am. Chem. Soc., 117, p. 704; Lodeiro, C., Parola, A.J., Pina, F., Bazzicalupi, C., Bencini, A., Bianchi, A., Giorgi, C., Valtancoli, B., Inorg. Chem., 40, p. 2968; Altomare, A., Burla, M.C., Camalli, M., Cascarano, G.L., Giacovazzo, C., Guagliardi, A., Moliterni, A.G.G., Spagna, R., J. Appl. Crystallogr., 32, p. 115; Sheldrick, G.M., SHELXL97, , University of G{\"o}ttingen, Germany; Bianchi, A., Bologni, L., Dapporto, P., Micheloni, M., Paoletti, P., Inorg. Chem., 23, p. 1201; Gran, G., Analyst (London), 77, p. 661; Gans, P., Sabatini, A., Vacca, A., Talanta, 43, p. 1739; Stricker, G., Subramaniam, V., Seidel, C.A.M., Volkmer, A., J. Phys. Chem. B, 103, p. 8612; Seixas de Melo, J., Elisei, F., Gartner, C., Aloisi, G., Becker, R.S., J. Phys. Chem. A, 104, p. 6907; Farrugia, L.J., ORTEP-3 Windows version 1.01 beta, , Department of Chemistry: Universty of Glasgow; Rillema, D.P., Jones, D.S., Woods, C., Levy, H.A., Inorg. Chem., 31, p. 2935; Janiak, C., J. Chem. Soc., Dalton Trans., p. 3885; Bencini, A., Bianchi, A., Garcia-Espa{\~n}a, E., Micheloni, M., Ramirez, J.A., Coord. Chem. Rev., 188, p. 97; Alderighi, L., Gans, P., Ienco, A., Peters, D., Sabatini, A., Vacca, A., Coord. Chem. Rev., 184, p. 311; Smith, R.M., Martell, A.E., NIST Critical Stability Constants Database, version 2, , National Institute of Standards and Technology: Washington, DC; Bianchi, A., Bowman-James, K., Garcia-Espa{\~n}a, E., Supramolecular Chemistry of Anions, , Wiley-VCH: New York; Peter, F., Gross, M., Hosseini, M.W., Lehn, J.-M., Sessions, R.B., J. Chem. Soc., Chem. Commun., p. 1067; Peter, F., Gross, M., Hosseini, M.W., Lehn, J.-M., Electroanal Chem., 144, p. 279; Garcia-Espa{\~n}a, E., Micheloni, M., Paoletti, P., Bianchi, A., Inorg. Chim. Acta, 102, pp. L9; Bencini, A., Bianchi, A., Garcia-Espa{\~n}a, E., Giusti, M., Mangani, S., Micheloni, M., Orioli, P., Paoletti, P., Inorg. Chem., 26, p. 3902; Arag{\'o}, J., Bencini, A., Bianchi, A., Domenech, A., Garcia-Espa{\~n}a, E., J. Chem. Soc., Dalton Trans., p. 319; Bianchi, A., Domenech, A., Garcia-Espa{\~n}a, E., Luis, S., Anal. Chem., 65, p. 3137; Juris, A., Gandolfi, M.T., Manfrin, M.F., Balzani, V., J. Am. Chem. Soc., 98, p. 1047; Mallouk, T.E., Krueger, J.S., Mayer, J.E., Dymond, C.M.G., Inorg. Chem., 28, p. 3507; Roundhill, D.M., Photochemistry and Photophysics of Metal Complexes, , Plenum Press: New York; Pina, F., Ciano, M., Moggi, L., Balzani, V., Inorg. Chem., 24, p. 844; Pina, F., Maestri, M., Ballardini, R., Mulazzani, Q.G., D'Angelantonio, M., Balzani, V., Inorg. Chem., 25, p. 4249; Pina, F., Sotomayor, J., Moggi, L., J. Photochem. Photobiol. A, 53, p. 411",

year = "2001",

month = dec,

day = "17",

doi = "10.1021/ic0105213",

language = "English",

volume = "40",

pages = "6813--6819",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "ACS - American Chemical Society",

number = "26",

}

Lodeiro, C , Pina, F , Parola, AJ, Bencini, A, Bianchi, A, Bazzicalupi, C, Ciattini, S, Giorgi, C, Masotti, A, Valtancoli, B & Seixas de Melo, J 2001, 'Exploring the photocatalytic properties and the long-lifetime chemosensor ability of CI2[Ru(Bpy)2L] (L = 2,5,8,11,14-pentaaza[15])-2,2′-bipyridilophane)', Inorganic Chemistry, vol. 40, no. 26, pp. 6813-6819. https://doi.org/10.1021/ic0105213

TY - JOUR

T1 - Exploring the photocatalytic properties and the long-lifetime chemosensor ability of CI2[Ru(Bpy)2L] (L = 2,5,8,11,14-pentaaza[15])-2,2′-bipyridilophane)

AU - Lodeiro, C.

AU - Pina, F.

AU - Parola, A.J.

AU - Bencini, Andrea

AU - Bianchi, Antonio

AU - Bazzicalupi, Caria

AU - Ciattini, S.

AU - Giorgi, Claudia

AU - Masotti, A.

AU - Valtancoli, Barbara

AU - Seixas de Melo, J.

N1 - Cited By :21 Export Date: 7 May 2017 CODEN: INOCA Correspondence Address: Lodeiro, C.; Departamento de Química, Centro Quimica-Fina e Biotecnologia, Faculdade de Ciencias e Tecnologia, Quinta da Torre 2825, Monte de Caparica, Portugal; email: [email protected] References: Pina, F., Bernardo, M.A., Garciá-España, E., Eur. J. Inorg. Chem., p. 2143; Bazzicalupi, C., Bencini, A., Bianchi, A., Giorgi, C., Fusi, V., Valtancoli, B., Bernardo, M.A., Pina, F., Inorg. Chem., 38, p. 3806; Czarnik, A.W., Acc. Chem. Res., 27, p. 302; Czarnik, A.W., Fluorescent Chemosensors for Ion Molecule and Recognition, , American Chemical Society: Washington DC; Bissel, R.A., De Silva, A.P., Gunaratne, H.Q.N., Lynch, P.L.M., Maguaire, G.E.M., Sandanayake, K.R.A.S., Chem. Soc. Rev., p. 187; De Silva, A.P., Gunaratne, H.Q.N., Gunnlaugsson, T., Huxley, A.J.M., McCoy, C.P., Rademacher, J.T., Rice, T.E., Chem. Rev., 97, p. 1515; Lakowicz, J.R., Probe design and chemical sensing, , Topics in Fluorescence Spectroscopy 4; Plenum Press: New York; Murtaza, Z., Chang, Q., Rao, G., Lin, H., Lakowicz, J.R., Anal. Biochem., 247, p. 216; Grigg, R., Norbert, W.D.J.A., J. Chem. Soc. Chem. Commun., p. 1300; Kimura, E., Wada, S., Shionoya, M., Takahashi, T., Litaka, Y., J. Chem. Soc. Chem. Commun., p. 397; Rawle, S.C., Moore, P., Alcock, N.W., J. Chem. Soc., Chem. Commun., p. 684; Alcock, N.W., Clarke, A.J., Errington, W., Josceanu, A.M., Moore, P., Rawle, S.C., Sheldon, P., Turonek, M., Supramol. Chem., 6, p. 281. , and references therein; Szemes, F., Hesek, D., Chen, Z., Dent, S.W., Drew, M.G.B., Goulden, A.J., Graydon, A.R., Beer, P.D., Inorg. Chem., 35, p. 5868; Beer, P.D., Szemes, F., Balzani, V., Salaà, C.M., Drew, M.G.B., Dent, S.W., Maestri, M., J. Am. Chem. Soc., 119, p. 11864; Beer, P.D., Acc. Chem. Res., 31, p. 71; Beer, P.D., Gale, P.A., Angew. Chem., Int. Ed., 40, p. 486; Beer, P.D., Cadman, J., New J. Chem., 23, p. 347; Turro, C., Chang, C.K., Leroi, G.E., Cukier, R.I., Nocera, D.G., J. Am. Chem. Soc., 114, p. 4013; Roberts, J.A., Kirby, J.P., Nocera, D.G., J. Am. Chem. Soc., 117, p. 8051; Deng, Y., Roberts, J.A., Peng, S.M., Chang, C.K., Nocera, D.G., Angew. Chem., Int. Ed. Engl., 36, p. 2124; Kirby, J.P., Roberts, J.A., Nocera, D.G., J. Am. Chem. Soc., 119, p. 9230; Harriman, A., Magda, D.J., Sessler, J.L., J. Phys. Chem. B, 95, p. 1530; Harriman, A., Magda, D.J., Sessler, J.L., J. Chem. Soc., Chem. Commun., p. 345; Harriman, A., Kubo, Y., Sessler, J.L., J. Am. Chem. Soc., 114, p. 388; Harriman, A., Bing, W., Sessler, J.L., J. Am. Chem. Soc., 115, p. 10418; Harriman, A., Bing, W., Sessler, J.L., J. Am. Chem. Soc., 117, p. 704; Lodeiro, C., Parola, A.J., Pina, F., Bazzicalupi, C., Bencini, A., Bianchi, A., Giorgi, C., Valtancoli, B., Inorg. Chem., 40, p. 2968; Altomare, A., Burla, M.C., Camalli, M., Cascarano, G.L., Giacovazzo, C., Guagliardi, A., Moliterni, A.G.G., Spagna, R., J. Appl. Crystallogr., 32, p. 115; Sheldrick, G.M., SHELXL97, , University of Göttingen, Germany; Bianchi, A., Bologni, L., Dapporto, P., Micheloni, M., Paoletti, P., Inorg. Chem., 23, p. 1201; Gran, G., Analyst (London), 77, p. 661; Gans, P., Sabatini, A., Vacca, A., Talanta, 43, p. 1739; Stricker, G., Subramaniam, V., Seidel, C.A.M., Volkmer, A., J. Phys. Chem. B, 103, p. 8612; Seixas de Melo, J., Elisei, F., Gartner, C., Aloisi, G., Becker, R.S., J. Phys. Chem. A, 104, p. 6907; Farrugia, L.J., ORTEP-3 Windows version 1.01 beta, , Department of Chemistry: Universty of Glasgow; Rillema, D.P., Jones, D.S., Woods, C., Levy, H.A., Inorg. Chem., 31, p. 2935; Janiak, C., J. Chem. Soc., Dalton Trans., p. 3885; Bencini, A., Bianchi, A., Garcia-España, E., Micheloni, M., Ramirez, J.A., Coord. Chem. Rev., 188, p. 97; Alderighi, L., Gans, P., Ienco, A., Peters, D., Sabatini, A., Vacca, A., Coord. Chem. Rev., 184, p. 311; Smith, R.M., Martell, A.E., NIST Critical Stability Constants Database, version 2, , National Institute of Standards and Technology: Washington, DC; Bianchi, A., Bowman-James, K., Garcia-España, E., Supramolecular Chemistry of Anions, , Wiley-VCH: New York; Peter, F., Gross, M., Hosseini, M.W., Lehn, J.-M., Sessions, R.B., J. Chem. Soc., Chem. Commun., p. 1067; Peter, F., Gross, M., Hosseini, M.W., Lehn, J.-M., Electroanal Chem., 144, p. 279; Garcia-España, E., Micheloni, M., Paoletti, P., Bianchi, A., Inorg. Chim. Acta, 102, pp. L9; Bencini, A., Bianchi, A., Garcia-España, E., Giusti, M., Mangani, S., Micheloni, M., Orioli, P., Paoletti, P., Inorg. Chem., 26, p. 3902; Aragó, J., Bencini, A., Bianchi, A., Domenech, A., Garcia-España, E., J. Chem. Soc., Dalton Trans., p. 319; Bianchi, A., Domenech, A., Garcia-España, E., Luis, S., Anal. Chem., 65, p. 3137; Juris, A., Gandolfi, M.T., Manfrin, M.F., Balzani, V., J. Am. Chem. Soc., 98, p. 1047; Mallouk, T.E., Krueger, J.S., Mayer, J.E., Dymond, C.M.G., Inorg. Chem., 28, p. 3507; Roundhill, D.M., Photochemistry and Photophysics of Metal Complexes, , Plenum Press: New York; Pina, F., Ciano, M., Moggi, L., Balzani, V., Inorg. Chem., 24, p. 844; Pina, F., Maestri, M., Ballardini, R., Mulazzani, Q.G., D'Angelantonio, M., Balzani, V., Inorg. Chem., 25, p. 4249; Pina, F., Sotomayor, J., Moggi, L., J. Photochem. Photobiol. A, 53, p. 411

PY - 2001/12/17

Y1 - 2001/12/17

N2 - In this work a new water-soluble long-lifetime chemosensor, containing a polyamine unit connected to a complexed Ru(II) metal center, is described. Its crystal structure has been characterized by X-ray analysis. The polyamine macrocyclic unit is capable of anchoring cationic or anionic substrates, according to its protonation state. Examples of electron transfer involving the ruthenium complex core and the bound substrate are presented. The photocatalytic ability of such a system is illustrated by the oxidation of iodide to iodine promoted by light absorption at 436 nm.

AB - In this work a new water-soluble long-lifetime chemosensor, containing a polyamine unit connected to a complexed Ru(II) metal center, is described. Its crystal structure has been characterized by X-ray analysis. The polyamine macrocyclic unit is capable of anchoring cationic or anionic substrates, according to its protonation state. Examples of electron transfer involving the ruthenium complex core and the bound substrate are presented. The photocatalytic ability of such a system is illustrated by the oxidation of iodide to iodine promoted by light absorption at 436 nm.

KW - metal complex

KW - ruthenium derivative

KW - article

KW - catalysis

KW - chemosensitivity

KW - crystal structure

KW - electron transport

KW - photochemistry

KW - sensor

U2 - 10.1021/ic0105213

DO - 10.1021/ic0105213

M3 - Article

SN - 0020-1669

VL - 40

SP - 6813

EP - 6819

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 26

ER -

Exploring the photocatalytic properties and the long-lifetime chemosensor ability of CI2[Ru(Bpy)2L] (L = 2,5,8,11,14-pentaaza[15])-2,2′-bipyridilophane)

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