@article{4609ad7162bf46d4bfee17105feac21d,
title = "Exploring the photocatalytic properties and the long-lifetime chemosensor ability of CI2[Ru(Bpy)2L] (L = 2,5,8,11,14-pentaaza[15])-2,2′-bipyridilophane)",
abstract = "In this work a new water-soluble long-lifetime chemosensor, containing a polyamine unit connected to a complexed Ru(II) metal center, is described. Its crystal structure has been characterized by X-ray analysis. The polyamine macrocyclic unit is capable of anchoring cationic or anionic substrates, according to its protonation state. Examples of electron transfer involving the ruthenium complex core and the bound substrate are presented. The photocatalytic ability of such a system is illustrated by the oxidation of iodide to iodine promoted by light absorption at 436 nm.",
keywords = "metal complex, ruthenium derivative, article, catalysis, chemosensitivity, crystal structure, electron transport, photochemistry, sensor",
author = "C. Lodeiro and F. Pina and A.J. Parola and Andrea Bencini and Antonio Bianchi and Caria Bazzicalupi and S. Ciattini and Claudia Giorgi and A. Masotti and Barbara Valtancoli and {Seixas de Melo}, J.",
note = "Cited By :21 Export Date: 7 May 2017 CODEN: INOCA Correspondence Address: Lodeiro, C.; Departamento de Qu{\'i}mica, Centro Quimica-Fina e Biotecnologia, Faculdade de Ciencias e Tecnologia, Quinta da Torre 2825, Monte de Caparica, Portugal; email: fjp@dq.fct.unl.pt References: Pina, F., Bernardo, M.A., Garci{\'a}-Espa{\~n}a, E., Eur. J. Inorg. Chem., p. 2143; Bazzicalupi, C., Bencini, A., Bianchi, A., Giorgi, C., Fusi, V., Valtancoli, B., Bernardo, M.A., Pina, F., Inorg. Chem., 38, p. 3806; Czarnik, A.W., Acc. Chem. Res., 27, p. 302; Czarnik, A.W., Fluorescent Chemosensors for Ion Molecule and Recognition, , American Chemical Society: Washington DC; Bissel, R.A., De Silva, A.P., Gunaratne, H.Q.N., Lynch, P.L.M., Maguaire, G.E.M., Sandanayake, K.R.A.S., Chem. Soc. Rev., p. 187; De Silva, A.P., Gunaratne, H.Q.N., Gunnlaugsson, T., Huxley, A.J.M., McCoy, C.P., Rademacher, J.T., Rice, T.E., Chem. 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year = "2001",
month = dec,
day = "17",
doi = "10.1021/ic0105213",
language = "English",
volume = "40",
pages = "6813--6819",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "ACS - American Chemical Society",
number = "26",
}