TY - JOUR
T1 - Emerging Ionic Polymers for CO2Conversion to Cyclic Carbonates
T2 - An Overview of Recent Developments
AU - Jamil, Rabia
AU - Tomé, Liliana C.
AU - Mecerreyes, David
AU - Silvester, Debbie S.
N1 - Funding Information:
info:eu-repo/grantAgreement/FCT/CEEC IND 3ed/2020.01555.CEECIND%2FCP1586%2FCT0034/PT#
info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50006%2F2020/PT#
info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50006%2F2020/PT#
D.S.S. thanks the Australian Research Council for funding through a Future Fellowship (FT170100315). DM thanks the Agencia Española de Investigación (AEI) for funding through project PID2020–119026GB-I00.
Publisher Copyright:
© 2021 Journal Compilation.
PY - 2021/12
Y1 - 2021/12
N2 - In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application include materials such as poly(ionic liquid)s (PILs), ionic porous organic polymers (iPOPs) or ionic covalent organic frameworks (iCOFs) among others. All these organic materials share in common the ionic moiety cations such as imidazolium, pyridinium, viologen, ammonium, phosphonium, and guanidinium, and anions such as halides, [BF4]-, [PF6]-, and [Tf2N]-. The mechanistic aspects and efficiency of the CO2 conversion reaction and the polymer design including functional groups and porosity are discussed in detail. This review should provide valuable information for researchers to design new polymers for important catalysis applications.
AB - In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application include materials such as poly(ionic liquid)s (PILs), ionic porous organic polymers (iPOPs) or ionic covalent organic frameworks (iCOFs) among others. All these organic materials share in common the ionic moiety cations such as imidazolium, pyridinium, viologen, ammonium, phosphonium, and guanidinium, and anions such as halides, [BF4]-, [PF6]-, and [Tf2N]-. The mechanistic aspects and efficiency of the CO2 conversion reaction and the polymer design including functional groups and porosity are discussed in detail. This review should provide valuable information for researchers to design new polymers for important catalysis applications.
KW - catalysts
KW - COconversion
KW - COfixation
KW - cycloaddition reaction
KW - heterogeneous catalysis
KW - ionic liquids
KW - poly(ionic liquids)
KW - polymers
UR - http://www.scopus.com/inward/record.url?scp=85118223764&partnerID=8YFLogxK
U2 - 10.1071/CH21182
DO - 10.1071/CH21182
M3 - Review article
AN - SCOPUS:85118223764
SN - 0004-9425
VL - 74
SP - 767
EP - 777
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 11(SI)
ER -