TY - JOUR
T1 - Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
T2 - A Combined Single-Crystal X-ray Diffraction and Hirshfeld Analysis Approach
AU - Machado, Beatriz P.
AU - Celador-Garcia, Maria
AU - Rosa, Vítor
AU - Gomes, Clara S. B.
N1 - Funding Information:
info:eu-repo/grantAgreement/FCT/Concurso de avaliação no âmbito do Programa Plurianual de Financiamento de Unidades de I&D (2017%2F2018) - Financiamento Base/UIDB%2F50006%2F2020/PT#
info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50006%2F2020/PT#
info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0008%2F2020/PT#
Publisher Copyright:
© 2024 by the authors.
PY - 2024/5/4
Y1 - 2024/5/4
N2 - Dimeric bismuth(III) complexes bearing bis(aryl-imino)acenaphthene (Aryl-BIAN) donor ligands of the general formulae [(Dipp-BIAN)BiCl3]2 2, [(o-iPr-BIAN)BiCl3]2 3, and [(p-iPr-BIAN)BiCl3]2 4, where Dipp = diisopropyl, o-iPr = ortho-isopropyl and p-iPr = para-isopropyl, were prepared by reaction of the corresponding neutral BIAN ligand with BiCl3, under inert atmosphere conditions. X-ray studies were performed, and their molecular structures were determined. The individual contributions of intermolecular interactions to crystal packing have been quantified by means of Hirsfeld surface analysis.
AB - Dimeric bismuth(III) complexes bearing bis(aryl-imino)acenaphthene (Aryl-BIAN) donor ligands of the general formulae [(Dipp-BIAN)BiCl3]2 2, [(o-iPr-BIAN)BiCl3]2 3, and [(p-iPr-BIAN)BiCl3]2 4, where Dipp = diisopropyl, o-iPr = ortho-isopropyl and p-iPr = para-isopropyl, were prepared by reaction of the corresponding neutral BIAN ligand with BiCl3, under inert atmosphere conditions. X-ray studies were performed, and their molecular structures were determined. The individual contributions of intermolecular interactions to crystal packing have been quantified by means of Hirsfeld surface analysis.
KW - bis(arylimino)acenaphthene (Aryl-BIAN) ligands
KW - bismuth
KW - Hirshfeld surface analysis
KW - X-ray structure
UR - http://www.scopus.com/inward/record.url?scp=85194262467&partnerID=8YFLogxK
U2 - 10.3390/inorganics12050135
DO - 10.3390/inorganics12050135
M3 - Article
AN - SCOPUS:85194262467
SN - 2304-6740
VL - 12
JO - Inorganics
JF - Inorganics
IS - 5
M1 - 135
ER -