Elastic differential cross sections for C4F6 isomers in the 1.5-200 eV energy electron impact: Similarities with six fluorine containing molecules and evidence of F-atom like scattering

Masamitsu Hoshino, P. Limao-Vieira, Kazutoshi Anzai, Hidetoshi Kato, Hyuck Cho, Daisuke Mogi, T. Tanioka, F. Ferreira da Silva, Diogo Almeida, Francisco Blanco, Gustavo Garcia, Oddur Ingolfsson, Hiroshi Tanaka

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Abstract

We report absolute elastic differential cross sections for electron interactions with the C4F6 isomers, hexafluoro-1,3-butadiene (1,3-C4F6), hexafluoro-2-butyne (2-C4F6), and hexafluorocyclobutene (c-C4F6). The incident electron energy range is 1.5-200 eV, and the scattered electron angular range for the differential measurements varies from 15 degrees to 150 degrees. In all cases the absolute scale of the differential cross section was set using the relative flow technique, with helium as the reference species. Atomic-like behaviour in these scattering systems is shown here for the first time, and is further investigated by comparing the elastic cross sections for the C4F6 isomers with other fluorinated molecules, such as SF6 and CnF6 (n = 2, 3, and 6). We note that for all the six-F containing molecules, the scattering process for electron energies above 30 eV is indistinguishable. Finally, we report results for calculations of elastic differential cross sections for electron scattering from each of these isomers, within an optical potential method and assuming a screened corrected independent atom representation. The level of agreement between these calculations and our measurements is found to be quite remarkable in all cases. (C) 2014 AIP Publishing LLC.
Original languageEnglish
Article number124302
JournalJournal of Chemical Physics
Volume141
Issue number12
DOIs
Publication statusPublished - 28 Sep 2014

Keywords

  • PERFLUOROCARBON COMPOUNDS
  • LOSS SPECTROSCOPY
  • ATTACHMENT
  • 1,3-C4F6; HEXAFLUORO-1,3-BUTADIENE
  • HELIUM;
  • C-C4F6
  • 2-C4F6
  • STATES
  • ARGON

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