(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

Mara F. Pinto; Marta Olivares; Ángela Vivancos; Gregorio Guisado-Barrios; Martin Albrecht; Beatriz Royo

doi:10.1039/c9cy00685k

(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

Mara F. Pinto, Marta Olivares, Ángela Vivancos, Gregorio Guisado-Barrios, Martin Albrecht, Beatriz Royo

Instituto de Tecnologia Química e Biológica António Xavier (ITQB)

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Carbonyl manganese complexes with chelating or bridging mesoionic di(1,2,3-triazolylidene) ligands were efficiently synthesised and fully characterised, including the X-ray diffraction study of a bimetallic manganese(0) complex. This unprecedented bimetallic complex displayed high yield and selectivity in the catalytic oxidation of secondary alcohols and benzyl alcohol with tert-butyl hydroperoxide under mild conditions.

Original language	English
Pages (from-to)	2421-2425
Number of pages	5
Journal	Catalysis Science and Technology
Volume	9
Issue number	10
DOIs	https://doi.org/10.1039/c9cy00685k
Publication status	Published - 1 Jan 2019

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T1 - (Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

AU - Pinto, Mara F.

AU - Olivares, Marta

AU - Vivancos, Ángela

AU - Guisado-Barrios, Gregorio

AU - Albrecht, Martin

AU - Royo, Beatriz

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Carbonyl manganese complexes with chelating or bridging mesoionic di(1,2,3-triazolylidene) ligands were efficiently synthesised and fully characterised, including the X-ray diffraction study of a bimetallic manganese(0) complex. This unprecedented bimetallic complex displayed high yield and selectivity in the catalytic oxidation of secondary alcohols and benzyl alcohol with tert-butyl hydroperoxide under mild conditions.

AB - Carbonyl manganese complexes with chelating or bridging mesoionic di(1,2,3-triazolylidene) ligands were efficiently synthesised and fully characterised, including the X-ray diffraction study of a bimetallic manganese(0) complex. This unprecedented bimetallic complex displayed high yield and selectivity in the catalytic oxidation of secondary alcohols and benzyl alcohol with tert-butyl hydroperoxide under mild conditions.

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U2 - 10.1039/c9cy00685k

DO - 10.1039/c9cy00685k

M3 - Article

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JO - Catalysis Science and Technology

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ER -

(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

Abstract

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