(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

Mara F. Pinto, Marta Olivares, Ángela Vivancos, Gregorio Guisado-Barrios, Martin Albrecht, Beatriz Royo

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Carbonyl manganese complexes with chelating or bridging mesoionic di(1,2,3-triazolylidene) ligands were efficiently synthesised and fully characterised, including the X-ray diffraction study of a bimetallic manganese(0) complex. This unprecedented bimetallic complex displayed high yield and selectivity in the catalytic oxidation of secondary alcohols and benzyl alcohol with tert-butyl hydroperoxide under mild conditions.

Original languageEnglish
Pages (from-to)2421-2425
Number of pages5
JournalCatalysis Science and Technology
Volume9
Issue number10
DOIs
Publication statusPublished - 1 Jan 2019

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