Diterpenoids from Salvia candelabrum

Eduarda Mendes; José L. Marco; Benjamin Rodríguez; María L. Jimeno; Ana M. Lobo; Sundaresan Prabhakar

doi:10.1016/S0031-9422(00)97825-7

Diterpenoids from Salvia candelabrum

Eduarda Mendes, José L. Marco, Benjamin Rodríguez, María L. Jimeno, Ana M. Lobo, Sundaresan Prabhakar

DQ - Departamento de Química

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

From the aerial parts of Salvia candelabrum two new rearranged abietane diterpenoids, candesalvones A and B, have been isolated besides β-sitosterol, nepeticin [lup-20(29)-ene-3β,11α-diol], candelabrone [11,12,14-trihydroxy-8,11,13-abietatriene-3,7-dione) and large amounts of ursolic and oleanolic acids. The structures of candesalvone A[11,12,14-trihydroxy-19(4→3)-abeo-3,8,11,13-abietatetraen-7-one] and candesalvone B [11,12,14-trihydroxy-7-oxo-3,4-seco-4(18),8,11,13-abietatetraen-3-oic acid] were established by chemical and spectroscopic means. In addition, the root bark of the same species afforded the previously known abietane derivatives 7α-acetoxyroyleanone, 12-O-methylpisiferic acid and sugiol.

Original language	English
Pages (from-to)	1685-1690
Number of pages	6
Journal	Phytochemistry
Volume	28
Issue number	6
DOIs	https://doi.org/10.1016/S0031-9422(00)97825-7
Publication status	Published - 1 Jan 1989

Keywords

19(4→3)-abeo-abietane derivative
3,4-seco-abietane derivative
abietane diterpenoids
candesalvones A and B.
Labiatae
Salvia candelabrum

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title = "Diterpenoids from Salvia candelabrum",

abstract = "From the aerial parts of Salvia candelabrum two new rearranged abietane diterpenoids, candesalvones A and B, have been isolated besides β-sitosterol, nepeticin [lup-20(29)-ene-3β,11α-diol], candelabrone [11,12,14-trihydroxy-8,11,13-abietatriene-3,7-dione) and large amounts of ursolic and oleanolic acids. The structures of candesalvone A[11,12,14-trihydroxy-19(4→3)-abeo-3,8,11,13-abietatetraen-7-one] and candesalvone B [11,12,14-trihydroxy-7-oxo-3,4-seco-4(18),8,11,13-abietatetraen-3-oic acid] were established by chemical and spectroscopic means. In addition, the root bark of the same species afforded the previously known abietane derivatives 7α-acetoxyroyleanone, 12-O-methylpisiferic acid and sugiol.",

keywords = "19(4→3)-abeo-abietane derivative, 3,4-seco-abietane derivative, abietane diterpenoids, candesalvones A and B., Labiatae, Salvia candelabrum",

author = "Eduarda Mendes and Marco, {Jos{\'e} L.} and Benjamin Rodr{\'i}guez and Jimeno, {Mar{\'i}a L.} and Lobo, {Ana M.} and Sundaresan Prabhakar",

year = "1989",

month = jan,

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doi = "10.1016/S0031-9422(00)97825-7",

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pages = "1685--1690",

journal = "Phytochemistry",

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TY - JOUR

T1 - Diterpenoids from Salvia candelabrum

AU - Mendes, Eduarda

AU - Marco, José L.

AU - Rodríguez, Benjamin

AU - Jimeno, María L.

AU - Lobo, Ana M.

AU - Prabhakar, Sundaresan

PY - 1989/1/1

Y1 - 1989/1/1

N2 - From the aerial parts of Salvia candelabrum two new rearranged abietane diterpenoids, candesalvones A and B, have been isolated besides β-sitosterol, nepeticin [lup-20(29)-ene-3β,11α-diol], candelabrone [11,12,14-trihydroxy-8,11,13-abietatriene-3,7-dione) and large amounts of ursolic and oleanolic acids. The structures of candesalvone A[11,12,14-trihydroxy-19(4→3)-abeo-3,8,11,13-abietatetraen-7-one] and candesalvone B [11,12,14-trihydroxy-7-oxo-3,4-seco-4(18),8,11,13-abietatetraen-3-oic acid] were established by chemical and spectroscopic means. In addition, the root bark of the same species afforded the previously known abietane derivatives 7α-acetoxyroyleanone, 12-O-methylpisiferic acid and sugiol.

AB - From the aerial parts of Salvia candelabrum two new rearranged abietane diterpenoids, candesalvones A and B, have been isolated besides β-sitosterol, nepeticin [lup-20(29)-ene-3β,11α-diol], candelabrone [11,12,14-trihydroxy-8,11,13-abietatriene-3,7-dione) and large amounts of ursolic and oleanolic acids. The structures of candesalvone A[11,12,14-trihydroxy-19(4→3)-abeo-3,8,11,13-abietatetraen-7-one] and candesalvone B [11,12,14-trihydroxy-7-oxo-3,4-seco-4(18),8,11,13-abietatetraen-3-oic acid] were established by chemical and spectroscopic means. In addition, the root bark of the same species afforded the previously known abietane derivatives 7α-acetoxyroyleanone, 12-O-methylpisiferic acid and sugiol.

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KW - 3,4-seco-abietane derivative

KW - abietane diterpenoids

KW - candesalvones A and B.

KW - Labiatae

KW - Salvia candelabrum

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VL - 28

SP - 1685

EP - 1690

JO - Phytochemistry

JF - Phytochemistry

IS - 6

ER -

Diterpenoids from Salvia candelabrum

Abstract

Keywords

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