Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water

Maxime Guitet, Filipa Marcelo, Ségolène Adam De Beaumais, Yongmin Zhang, Jesús Jiménez-Barbero, Sébastien Tilloy, Eric Monflier, Mickaël Ménand, Matthieu Sollogoub

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32 Citations (Scopus)

Abstract

Two carbene-based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki-Miyaura coupling reactions both in ethanol and water. Two carbene-based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki-Miyaura coupling reactions both in ethanol and water.

Original languageEnglish
Pages (from-to)3691-3699
Number of pages9
JournalEuropean Journal of Organic Chemistry
Issue number18
DOIs
Publication statusPublished - 1 Jun 2013

Keywords

  • Carbene ligands
  • Cyclodextrins
  • Homogeneous catalysis
  • Nitrogen heterocycles
  • Palladium

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