Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water

Maxime Guitet; Filipa Marcelo; Ségolène Adam De Beaumais; Yongmin Zhang; Jesús Jiménez-Barbero; Sébastien Tilloy; Eric Monflier; Mickaël Ménand; Matthieu Sollogoub

doi:10.1002/ejoc.201300190

Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water

Maxime Guitet, Filipa Marcelo, Ségolène Adam De Beaumais, Yongmin Zhang, Jesús Jiménez-Barbero, Sébastien Tilloy, Eric Monflier, Mickaël Ménand, Matthieu Sollogoub

CQFB-REQUIMTE - Centro de Química Fina e Biotecnologia (Lab. Associado REQUIMTE)

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38 Citations (Scopus)

Abstract

Two carbene-based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki-Miyaura coupling reactions both in ethanol and water. Two carbene-based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki-Miyaura coupling reactions both in ethanol and water.

Original language	English
Pages (from-to)	3691-3699
Number of pages	9
Journal	European Journal of Organic Chemistry
Issue number	18
DOIs	https://doi.org/10.1002/ejoc.201300190
Publication status	Published - 1 Jun 2013

Keywords

Carbene ligands
Cyclodextrins
Homogeneous catalysis
Nitrogen heterocycles
Palladium

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10.1002/ejoc.201300190Licence: CC BY-NC

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Guitet, M., Marcelo, F., De Beaumais, S. A., Zhang, Y., Jiménez-Barbero, J., Tilloy, S., Monflier, E., Ménand, M., & Sollogoub, M. (2013). Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water. European Journal of Organic Chemistry, (18), 3691-3699. https://doi.org/10.1002/ejoc.201300190

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title = "Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water",

abstract = "Two carbene-based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki-Miyaura coupling reactions both in ethanol and water. Two carbene-based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki-Miyaura coupling reactions both in ethanol and water.",

keywords = "Carbene ligands, Cyclodextrins, Homogeneous catalysis, Nitrogen heterocycles, Palladium",

author = "Maxime Guitet and Filipa Marcelo and {De Beaumais}, {S{\'e}gol{\`e}ne Adam} and Yongmin Zhang and Jes{\'u}s Jim{\'e}nez-Barbero and S{\'e}bastien Tilloy and Eric Monflier and Micka{\"e}l M{\'e}nand and Matthieu Sollogoub",

note = "The authors also thank the Agence Nationale de la Recherche (ANR) (Supra-HierArchi Project ANR-Blanc SIMI 7-2012) and the Portuguese Fundacao do Ministerio de Ciencia e Tecnologia (FCT) for a post-doctoral research grant (SFRH/BPD/65462/2009). The group at Madrid thanks the Spanish Ministerio de Economia y Competitividad (MINECO) (grant number CTQ2012-32025), the Comunidad de Madrid (MHit project), and the European Union (EU) (GlycoHit and Glycopharm projects, and COST actions CM1102 and BM1003).",

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doi = "10.1002/ejoc.201300190",

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Guitet, M, Marcelo, F, De Beaumais, SA, Zhang, Y, Jiménez-Barbero, J, Tilloy, S, Monflier, E, Ménand, M & Sollogoub, M 2013, 'Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water', European Journal of Organic Chemistry, no. 18, pp. 3691-3699. https://doi.org/10.1002/ejoc.201300190

Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water. / Guitet, Maxime; Marcelo, Filipa; De Beaumais, Ségolène Adam et al.
In: European Journal of Organic Chemistry, No. 18, 01.06.2013, p. 3691-3699.

Research output: Contribution to journal › Article › peer-review

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T1 - Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water

AU - Guitet, Maxime

AU - Marcelo, Filipa

AU - De Beaumais, Ségolène Adam

AU - Zhang, Yongmin

AU - Jiménez-Barbero, Jesús

AU - Tilloy, Sébastien

AU - Monflier, Eric

AU - Ménand, Mickaël

AU - Sollogoub, Matthieu

N1 - The authors also thank the Agence Nationale de la Recherche (ANR) (Supra-HierArchi Project ANR-Blanc SIMI 7-2012) and the Portuguese Fundacao do Ministerio de Ciencia e Tecnologia (FCT) for a post-doctoral research grant (SFRH/BPD/65462/2009). The group at Madrid thanks the Spanish Ministerio de Economia y Competitividad (MINECO) (grant number CTQ2012-32025), the Comunidad de Madrid (MHit project), and the European Union (EU) (GlycoHit and Glycopharm projects, and COST actions CM1102 and BM1003).

PY - 2013/6/1

Y1 - 2013/6/1

N2 - Two carbene-based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki-Miyaura coupling reactions both in ethanol and water. Two carbene-based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki-Miyaura coupling reactions both in ethanol and water.

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KW - Carbene ligands

KW - Cyclodextrins

KW - Homogeneous catalysis

KW - Nitrogen heterocycles

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ER -

Diametrically opposed carbenes on an α-cyclodextrin: Synthesis, characterization of organometallic complexes and Suzuki-Miyaura coupling in ethanol and in water

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Keywords

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