Development of photocatalytic titanium dioxide membranes for degradation of recalcitrant compounds

Sandra Sanches, Clarisse Nunes, Paula C. Passarinho, Frederico C. Ferreira, Vanessa J. Pereira, João G. Crespo

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)


BACKGROUND: Immobilization of TiO2 photoactive nanoparticles on a nanofiltration membrane without loss of permselectivity properties is currently a challenge. In this study, immobilization of TiO2 nanoparticles on a ceramic commercial membrane surface by direct current reactive magnetron sputtering was addressed. The best membrane was compared with an unmodified membrane and a membrane modified by a generic chemical–physical method in terms of membrane permselectivity and photocatalytic properties. RESULTS: Magnetron sputtering was able to achieve similar photocatalytic activity to the chemical–physical method, where Evonik P25 TiO2 nanoparticles were used, while maintaining membrane rejection and permeability. The layer formed by magnetron sputtering exhibits uniformly distributed nanostructured columns, aligned perpendicularly to the membrane surface. Furthermore, the membrane hydrophilicity increase achieved is promising for fouling control. A shorter sputtering time and distance between the titanium target and the membrane were preferable to effectively degrade the pesticides diuron and chlorfenvinphos. Under optimum sputtering conditions, 95% and 78% increases were attained for the degradation of diuron and chlorfenvinphos, respectively, compared with the unmodified membrane. CONCLUSION: The photocatalytic membranes developed are potential candidates for the simultaneous retention and photocatalytic degradation of recalcitrant micropollutants. However, if the purpose is to retain low molecular weight molecules, retentive properties should be improved.

Original languageEnglish
Pages (from-to)1727-1737
Number of pages11
JournalJournal of Chemical Technology and Biotechnology
Issue number7
Publication statusPublished - 1 Jul 2017


  • chemical–physical deposition
  • membrane filtration
  • photocatalytic activity
  • pulsed DC reactive magnetron sputtering
  • TiO immobilization


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