Corona poling and electroactivity in a side-chain methacrylate copolymer

Paulo António Martins Ferreira Ribeiro; D. T. Balogh; José A. Giacometti

doi:10.1109/94.868079

Corona poling and electroactivity in a side-chain methacrylate copolymer

Paulo António Martins Ferreira Ribeiro, D. T. Balogh, José A. Giacometti

DF – Departamento de Física

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The corona poling process and the decay in electro-optic activity were investigated for sidechain methacrylate (MA) copolymers functionalized with different weight percentages of chromophore disperse red-13. In order to obtain the maximum electro-optic activity, the efficiency of the corona poling process was investigated. The poling time, temperature and grid voltage of the corona triode were varied. Also, it was found that the electro-optic decay depends on chromophore content, temperature and the cooling rate of samples at the end of the poling process. Experimental data were fitted using the Kohlrausch-Williams-Watts (KWW) stretched exponential function and parameters depending on temperature and thermal treatment, and their relationship with the poling process is briefly discussed.

Original language	English
Pages (from-to)	572-577
Number of pages	6
Journal	Ieee Transactions On Dielectrics And Electrical Insulation
Volume	7
Issue number	4
DOIs	https://doi.org/10.1109/94.868079
Publication status	Published - Aug 2000

Keywords

Corona
Nonlinear optics
Optical films
Optical polymers
Voltage
Temperature dependence
Optical materials
Glass
Indium tin oxide
Cooling
polymer blends
Dyes
Electro-optical effects
Dielectric polarization

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title = "Corona poling and electroactivity in a side-chain methacrylate copolymer",

abstract = "The corona poling process and the decay in electro-optic activity were investigated for sidechain methacrylate (MA) copolymers functionalized with different weight percentages of chromophore disperse red-13. In order to obtain the maximum electro-optic activity, the efficiency of the corona poling process was investigated. The poling time, temperature and grid voltage of the corona triode were varied. Also, it was found that the electro-optic decay depends on chromophore content, temperature and the cooling rate of samples at the end of the poling process. Experimental data were fitted using the Kohlrausch-Williams-Watts (KWW) stretched exponential function and parameters depending on temperature and thermal treatment, and their relationship with the poling process is briefly discussed.",

keywords = "generation, polystyrene, triode, 2nd-harmonic, langmuir, dynamics, poled, polymer-films, dielectric-relaxation, rotational, disperse, red-13, reorientation, Corona, Nonlinear optics, Optical films, Optical polymers, Voltage, Temperature dependence, Optical materials, Glass, Indium tin oxide, Cooling, polymer blends, Dyes, Electro-optical effects, Dielectric polarization",

author = "Ribeiro, {Paulo Ant{\'o}nio Martins Ferreira} and Balogh, {D. T.} and Giacometti, {Jos{\'e} A.}",

year = "2000",

month = aug,

doi = "10.1109/94.868079",

language = "English",

volume = "7",

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journal = "Ieee Transactions On Dielectrics And Electrical Insulation",

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TY - JOUR

T1 - Corona poling and electroactivity in a side-chain methacrylate copolymer

AU - Ribeiro, Paulo António Martins Ferreira

AU - Balogh, D. T.

AU - Giacometti, José A.

PY - 2000/8

Y1 - 2000/8

N2 - The corona poling process and the decay in electro-optic activity were investigated for sidechain methacrylate (MA) copolymers functionalized with different weight percentages of chromophore disperse red-13. In order to obtain the maximum electro-optic activity, the efficiency of the corona poling process was investigated. The poling time, temperature and grid voltage of the corona triode were varied. Also, it was found that the electro-optic decay depends on chromophore content, temperature and the cooling rate of samples at the end of the poling process. Experimental data were fitted using the Kohlrausch-Williams-Watts (KWW) stretched exponential function and parameters depending on temperature and thermal treatment, and their relationship with the poling process is briefly discussed.

AB - The corona poling process and the decay in electro-optic activity were investigated for sidechain methacrylate (MA) copolymers functionalized with different weight percentages of chromophore disperse red-13. In order to obtain the maximum electro-optic activity, the efficiency of the corona poling process was investigated. The poling time, temperature and grid voltage of the corona triode were varied. Also, it was found that the electro-optic decay depends on chromophore content, temperature and the cooling rate of samples at the end of the poling process. Experimental data were fitted using the Kohlrausch-Williams-Watts (KWW) stretched exponential function and parameters depending on temperature and thermal treatment, and their relationship with the poling process is briefly discussed.

KW - generation

KW - polystyrene

KW - triode

KW - 2nd-harmonic

KW - langmuir

KW - dynamics

KW - poled

KW - polymer-films

KW - dielectric-relaxation

KW - rotational

KW - disperse

KW - red-13

KW - reorientation

KW - Corona

KW - Nonlinear optics

KW - Optical films

KW - Optical polymers

KW - Voltage

KW - Temperature dependence

KW - Optical materials

KW - Glass

KW - Indium tin oxide

KW - Cooling

KW - polymer blends

KW - Dyes

KW - Electro-optical effects

KW - Dielectric polarization

U2 - 10.1109/94.868079

DO - 10.1109/94.868079

M3 - Article

SN - 1070-9878

VL - 7

SP - 572

EP - 577

JO - Ieee Transactions On Dielectrics And Electrical Insulation

JF - Ieee Transactions On Dielectrics And Electrical Insulation

IS - 4

ER -

Corona poling and electroactivity in a side-chain methacrylate copolymer

Abstract

Keywords

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