Conductive electrospun Polyaniline/Polyvinylpyrrolidone nanofibers: Electrical and morphological characterization of new yarns for electronic textiles

Patrícia Perdigão; Bruno Miguel Morais Faustino; Jaime Faria; João Paulo Canejo; João Paulo Borges; Isabel Ferreira; Ana Catarina Baptista

doi:10.3390/fib8040024

Conductive electrospun Polyaniline/Polyvinylpyrrolidone nanofibers: Electrical and morphological characterization of new yarns for electronic textiles

Patrícia Perdigão, Bruno Miguel Morais Faustino, Jaime Faria, João Paulo Canejo, João Paulo Borges, Isabel Ferreira, Ana Catarina Baptista

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

26 Downloads (Pure)

Abstract

Advanced functionalities textiles embedding electronic fibers, yarns and fabrics are a demand for innovative smart cloths. Conductive electrospun membranes and yarns based on polyaniline/polyvinylpyrrolidone (PANI/PVP) were investigated using the chemical modification of PANI instead of using conventional coating processes as in-situ polymerization. PANI was synthesized from the aniline monomer and the influence of the oxidant-to-monomer ratio on electrical conductivity was studied. The optimized conductivity of pellets made with pressed PANI powders was 21 S·cm^-1. Yarns were then prepared from the t-Boc-PANI/PVP electrospun membranes followed by PANI protonation to enhance their electrical properties. Using this methodology, electrospun membranes and yarns were produced with electrical conductivities of 1.7 x 10^-2 and 4.1 x 10^-4 S·cm^-1.

Original language	English
Article number	24
Journal	Fibers
Volume	8
Issue number	4
DOIs	https://doi.org/10.3390/fib8040024
Publication status	Published - 1 Apr 2020

Keywords

Conductive textile
Conductive yarn
Electrospinning
Polyaniline
Polyvinylpyrrolidone

Access to Document

10.3390/fib8040024Licence: CC BY

fibers-08-00024-v2Final published version, 1.7 MBLicence: CC BY

Cite this

@article{fe34650925434f29b60b82c2084eb78e,

title = "Conductive electrospun Polyaniline/Polyvinylpyrrolidone nanofibers: Electrical and morphological characterization of new yarns for electronic textiles",

abstract = "Advanced functionalities textiles embedding electronic fibers, yarns and fabrics are a demand for innovative smart cloths. Conductive electrospun membranes and yarns based on polyaniline/polyvinylpyrrolidone (PANI/PVP) were investigated using the chemical modification of PANI instead of using conventional coating processes as in-situ polymerization. PANI was synthesized from the aniline monomer and the influence of the oxidant-to-monomer ratio on electrical conductivity was studied. The optimized conductivity of pellets made with pressed PANI powders was 21 S·cm-1. Yarns were then prepared from the t-Boc-PANI/PVP electrospun membranes followed by PANI protonation to enhance their electrical properties. Using this methodology, electrospun membranes and yarns were produced with electrical conductivities of 1.7 x 10-2 and 4.1 x 10-4 S·cm-1.",

keywords = "Conductive textile, Conductive yarn, Electrospinning, Polyaniline, Polyvinylpyrrolidone",

author = "Patr{\'i}cia Perdig{\~a}o and Faustino, {Bruno Miguel Morais} and Jaime Faria and Canejo, {Jo{\~a}o Paulo} and Borges, {Jo{\~a}o Paulo} and Isabel Ferreira and Baptista, {Ana Catarina}",

note = "info:eu-repo/grantAgreement/EC/H2020/645241/EU# info:eu-repo/grantAgreement/EC/H2020/647596/EU# UID/CTM/50025/2019 ",

year = "2020",

month = apr,

day = "1",

doi = "10.3390/fib8040024",

language = "English",

volume = "8",

journal = "Fibers",

issn = "2079-6439",

publisher = "MDPI - Multidisciplinary Digital Publishing Institute",

number = "4",

}

TY - JOUR

T1 - Conductive electrospun Polyaniline/Polyvinylpyrrolidone nanofibers: Electrical and morphological characterization of new yarns for electronic textiles

AU - Perdigão, Patrícia

AU - Faustino, Bruno Miguel Morais

AU - Faria, Jaime

AU - Canejo, João Paulo

AU - Borges, João Paulo

AU - Ferreira, Isabel

AU - Baptista, Ana Catarina

N1 - info:eu-repo/grantAgreement/EC/H2020/645241/EU# info:eu-repo/grantAgreement/EC/H2020/647596/EU# UID/CTM/50025/2019

PY - 2020/4/1

Y1 - 2020/4/1

N2 - Advanced functionalities textiles embedding electronic fibers, yarns and fabrics are a demand for innovative smart cloths. Conductive electrospun membranes and yarns based on polyaniline/polyvinylpyrrolidone (PANI/PVP) were investigated using the chemical modification of PANI instead of using conventional coating processes as in-situ polymerization. PANI was synthesized from the aniline monomer and the influence of the oxidant-to-monomer ratio on electrical conductivity was studied. The optimized conductivity of pellets made with pressed PANI powders was 21 S·cm-1. Yarns were then prepared from the t-Boc-PANI/PVP electrospun membranes followed by PANI protonation to enhance their electrical properties. Using this methodology, electrospun membranes and yarns were produced with electrical conductivities of 1.7 x 10-2 and 4.1 x 10-4 S·cm-1.

AB - Advanced functionalities textiles embedding electronic fibers, yarns and fabrics are a demand for innovative smart cloths. Conductive electrospun membranes and yarns based on polyaniline/polyvinylpyrrolidone (PANI/PVP) were investigated using the chemical modification of PANI instead of using conventional coating processes as in-situ polymerization. PANI was synthesized from the aniline monomer and the influence of the oxidant-to-monomer ratio on electrical conductivity was studied. The optimized conductivity of pellets made with pressed PANI powders was 21 S·cm-1. Yarns were then prepared from the t-Boc-PANI/PVP electrospun membranes followed by PANI protonation to enhance their electrical properties. Using this methodology, electrospun membranes and yarns were produced with electrical conductivities of 1.7 x 10-2 and 4.1 x 10-4 S·cm-1.

KW - Conductive textile

KW - Conductive yarn

KW - Electrospinning

KW - Polyaniline

KW - Polyvinylpyrrolidone

UR - http://www.scopus.com/inward/record.url?scp=85083770867&partnerID=8YFLogxK

U2 - 10.3390/fib8040024

DO - 10.3390/fib8040024

M3 - Article

AN - SCOPUS:85083770867

SN - 2079-6439

VL - 8

JO - Fibers

JF - Fibers

IS - 4

M1 - 24

ER -

Conductive electrospun Polyaniline/Polyvinylpyrrolidone nanofibers: Electrical and morphological characterization of new yarns for electronic textiles

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this