Complete ligand loss in electron ionization of the weakly bound organometallic tungsten hexacarbonyl dimer

Michael Neustetter, Andreas Mauracher, Paulo Limão-Vieira, Stephan Denifl

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

We observed the bare W2 + metal cation upon electron ionization of the weakly bound W(CO)6 dimer. This metal cation can be only observed due to the fast conversion of the weak cluster bond into a strong covalent bond between the metal moieties.

Original languageEnglish
Pages (from-to)9893-9896
Number of pages4
JournalPhysical Chemistry Chemical Physics
Volume18
Issue number15
DOIs
Publication statusPublished - 21 Apr 2016

Keywords

  • CHEMICAL-VAPOR-DEPOSITION
  • APPEARANCE ENERGIES
  • ATTACHMENT
  • THRESHOLD
  • PRECURSOR
  • W(CO)(6)

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