Comparative study of dielectric relaxation spectra of electrically and thermally aged low density polyethylene

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Abstract

Low-density polyethylene (LDPE) films were thermally aged in a sodium chloride aqueous solution at constant temperature (thermal aging). Some of the samples were simultaneously immersed in solution and subjected to an electric AC field (electrical aging). The dielectric relaxation spectra at 30 °C in the range of 10-5 Hz to 105 Hz were obtained for unaged and aged samples. For the low frequency (LF) region (10-5 Hz to 10-1 Hz) the time domain technique was used. A lock-in amplifier was used for the 10-1 Hz to 101 Hz medium frequency (MF) region. While for the high frequency (HF), 10-1 Hz to 105 Hz, RLC bridge measurements were performed. The main differences can be seen between electrically, thermally aged and unaged LDPE in the HF and LF regions. The LF peak is a broad peak related to localized space charge injection driven by the electric field. For electrically aged samples this peak increases in an earlier stage of electrical aging, decreasing afterwards. While in thermally aged samples the peak amplitude always increases with aging time. Finally the HF shows the beginning of a peak due to the γ and β transitions. This peak decreases with aging disappearing for the most aged samples.

Original languageEnglish
Title of host publication2003 Annual Report Conference on Electrical Insulation and Dielectric Phenomena
Subtitle of host publicationOctober 19-22, 2003: Hyatt Regency Albuquerque: Albuquerque, New Mexico, USA
Place of PublicationPiscataway
PublisherIEEE Dielectrics and Electrical Insulation Society
Pages161-164
Number of pages4
ISBN (Print)0-7803-7910-1
DOIs
Publication statusPublished - 2003
Event2003 Annual Report: Conference on Electrical Insulation and Dieletric Phenomena - Albuquerque, United States
Duration: 19 Oct 200322 Oct 2003

Publication series

NameConference on Electrical Insulation and Dielectric Phenomena (CEIDP), Annual Report
ISSN (Print)0084-9162

Conference

Conference2003 Annual Report: Conference on Electrical Insulation and Dieletric Phenomena
Country/TerritoryUnited States
CityAlbuquerque
Period19/10/0322/10/03

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