Chemical-electric energy conversion effect in zirconia nanopowder systems

A. S. Doroshkevich; A. I. Lyubchyk; A. V. Shilo; T. Yu Zelenyak; V. A. Glazunova; V. V. Burhovetskiy; A. V. Saprykina; Kh T. Holmurodov; I. K. Nosolev; V. S. Doroshkevich; G. K. Volkova; T. E. Konstantinova; V. I. Bodnarchuk; P. P. Gladyshev; V. A. Turchenko; S. A. Sinyakina

doi:10.1134/S1027451017030053

Chemical-electric energy conversion effect in zirconia nanopowder systems

A. S. Doroshkevich, A. I. Lyubchyk, A. V. Shilo, T. Yu Zelenyak, V. A. Glazunova, V. V. Burhovetskiy, A. V. Saprykina, Kh T. Holmurodov, I. K. Nosolev, V. S. Doroshkevich, G. K. Volkova, T. E. Konstantinova, V. I. Bodnarchuk, P. P. Gladyshev, V. A. Turchenko, S. A. Sinyakina

Research output: Contribution to journal › Article

1 Citation (Scopus)

Abstract

Issues concerned with the energy conversion of exothermal heterophase processes are discussed using the physico-chemical interaction between ZrO₂–Y₂O₃ (3 mol %) nanopowder system and atmospheric moisture as an example. The electrical properties of an experimental sample are investigated upon moisture saturation in the case of a molecular-flow density gradient. A probable mechanism for the effect based on the theory of contact phenomena in semiconductors is proposed. The idea of developing chemical-electric converters fabricated from nanoscale materials with dielectric conduction is suggested.

Original language	English
Pages (from-to)	523-529
Number of pages	7
Journal	Journal of Surface Investigation
Volume	11
Issue number	3
DOIs	https://doi.org/10.1134/S1027451017030053
Publication status	Published - 1 May 2017

Keywords

adsorption
chemical-electric energy conversion
double electric layer
electrokinetic processes
nanoionics
nanoparticle
new energy sources
size effects

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10.1134/S1027451017030053

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Doroshkevich, A. S., Lyubchyk, A. I., Shilo, A. V., Zelenyak, T. Y., Glazunova, V. A., Burhovetskiy, V. V., Saprykina, A. V., Holmurodov, K. T., Nosolev, I. K., Doroshkevich, V. S., Volkova, G. K., Konstantinova, T. E., Bodnarchuk, V. I., Gladyshev, P. P., Turchenko, V. A., & Sinyakina, S. A. (2017). Chemical-electric energy conversion effect in zirconia nanopowder systems. Journal of Surface Investigation, 11(3), 523-529. https://doi.org/10.1134/S1027451017030053

Doroshkevich, A. S. ; Lyubchyk, A. I. ; Shilo, A. V. ; Zelenyak, T. Yu ; Glazunova, V. A. ; Burhovetskiy, V. V. ; Saprykina, A. V. ; Holmurodov, Kh T. ; Nosolev, I. K. ; Doroshkevich, V. S. ; Volkova, G. K. ; Konstantinova, T. E. ; Bodnarchuk, V. I. ; Gladyshev, P. P. ; Turchenko, V. A. ; Sinyakina, S. A. / Chemical-electric energy conversion effect in zirconia nanopowder systems. In: Journal of Surface Investigation. 2017 ; Vol. 11, No. 3. pp. 523-529.

@article{b7846afb7de74c8b8109212277f19dbb,

title = "Chemical-electric energy conversion effect in zirconia nanopowder systems",

abstract = "Issues concerned with the energy conversion of exothermal heterophase processes are discussed using the physico-chemical interaction between ZrO2–Y2O3 (3 mol %) nanopowder system and atmospheric moisture as an example. The electrical properties of an experimental sample are investigated upon moisture saturation in the case of a molecular-flow density gradient. A probable mechanism for the effect based on the theory of contact phenomena in semiconductors is proposed. The idea of developing chemical-electric converters fabricated from nanoscale materials with dielectric conduction is suggested.",

keywords = "adsorption, chemical-electric energy conversion, double electric layer, electrokinetic processes, nanoionics, nanoparticle, new energy sources, size effects",

author = "Doroshkevich, {A. S.} and Lyubchyk, {A. I.} and Shilo, {A. V.} and Zelenyak, {T. Yu} and Glazunova, {V. A.} and Burhovetskiy, {V. V.} and Saprykina, {A. V.} and Holmurodov, {Kh T.} and Nosolev, {I. K.} and Doroshkevich, {V. S.} and Volkova, {G. K.} and Konstantinova, {T. E.} and Bodnarchuk, {V. I.} and Gladyshev, {P. P.} and Turchenko, {V. A.} and Sinyakina, {S. A.}",

note = "sem pdf. H2020/MSCA/RISE/HUNTER/691010 project and supported by the Russian Foundation for Basic Research, project no. 16-33-50010.",

year = "2017",

month = may,

day = "1",

doi = "10.1134/S1027451017030053",

language = "English",

volume = "11",

pages = "523--529",

journal = "Journal Of Surface Investigation-X-Ray Synchrotron And Neutron Techniques",

issn = "1027-4510",

publisher = "Springer Science Business Media",

number = "3",

}

Doroshkevich, AS, Lyubchyk, AI, Shilo, AV, Zelenyak, TY, Glazunova, VA, Burhovetskiy, VV, Saprykina, AV, Holmurodov, KT, Nosolev, IK, Doroshkevich, VS, Volkova, GK, Konstantinova, TE, Bodnarchuk, VI, Gladyshev, PP, Turchenko, VA & Sinyakina, SA 2017, 'Chemical-electric energy conversion effect in zirconia nanopowder systems', Journal of Surface Investigation, vol. 11, no. 3, pp. 523-529. https://doi.org/10.1134/S1027451017030053

Chemical-electric energy conversion effect in zirconia nanopowder systems. / Doroshkevich, A. S.; Lyubchyk, A. I.; Shilo, A. V.; Zelenyak, T. Yu; Glazunova, V. A.; Burhovetskiy, V. V.; Saprykina, A. V.; Holmurodov, Kh T.; Nosolev, I. K.; Doroshkevich, V. S.; Volkova, G. K.; Konstantinova, T. E.; Bodnarchuk, V. I.; Gladyshev, P. P.; Turchenko, V. A.; Sinyakina, S. A.

In: Journal of Surface Investigation, Vol. 11, No. 3, 01.05.2017, p. 523-529.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Chemical-electric energy conversion effect in zirconia nanopowder systems

AU - Doroshkevich, A. S.

AU - Lyubchyk, A. I.

AU - Shilo, A. V.

AU - Zelenyak, T. Yu

AU - Glazunova, V. A.

AU - Burhovetskiy, V. V.

AU - Saprykina, A. V.

AU - Holmurodov, Kh T.

AU - Nosolev, I. K.

AU - Doroshkevich, V. S.

AU - Volkova, G. K.

AU - Konstantinova, T. E.

AU - Bodnarchuk, V. I.

AU - Gladyshev, P. P.

AU - Turchenko, V. A.

AU - Sinyakina, S. A.

N1 - sem pdf. H2020/MSCA/RISE/HUNTER/691010 project and supported by the Russian Foundation for Basic Research, project no. 16-33-50010.

PY - 2017/5/1

Y1 - 2017/5/1

N2 - Issues concerned with the energy conversion of exothermal heterophase processes are discussed using the physico-chemical interaction between ZrO2–Y2O3 (3 mol %) nanopowder system and atmospheric moisture as an example. The electrical properties of an experimental sample are investigated upon moisture saturation in the case of a molecular-flow density gradient. A probable mechanism for the effect based on the theory of contact phenomena in semiconductors is proposed. The idea of developing chemical-electric converters fabricated from nanoscale materials with dielectric conduction is suggested.

AB - Issues concerned with the energy conversion of exothermal heterophase processes are discussed using the physico-chemical interaction between ZrO2–Y2O3 (3 mol %) nanopowder system and atmospheric moisture as an example. The electrical properties of an experimental sample are investigated upon moisture saturation in the case of a molecular-flow density gradient. A probable mechanism for the effect based on the theory of contact phenomena in semiconductors is proposed. The idea of developing chemical-electric converters fabricated from nanoscale materials with dielectric conduction is suggested.

KW - adsorption

KW - chemical-electric energy conversion

KW - double electric layer

KW - electrokinetic processes

KW - nanoionics

KW - nanoparticle

KW - new energy sources

KW - size effects

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U2 - 10.1134/S1027451017030053

DO - 10.1134/S1027451017030053

M3 - Article

AN - SCOPUS:85020553376

VL - 11

SP - 523

EP - 529

JO - Journal Of Surface Investigation-X-Ray Synchrotron And Neutron Techniques

JF - Journal Of Surface Investigation-X-Ray Synchrotron And Neutron Techniques

SN - 1027-4510

IS - 3

ER -