Aryl-BIAN-Cu (II) Complexes: Structural Diversity in Neutral and Cationic Derivatives

Research output: Contribution to conferencePosterpeer-review

Abstract

In the last two decades, several synthetic methodologies have been developed towards more sustainable and economical processes. One of these is mechanochemistry, consisting of solid-state reactions, either by manual grinding of solid reagents, using a mortar and pestle, or by using a ball mill. Mechanochemistry has the advantages of being an effective and cheap technique, for the synthesis of both organic and inorganic/coordination compounds [1] and for various other applications in Green Chemistry. Herein, we report the synthesis of new neutral and cationic Cu(II) complexes of the type [Cu(aryl-BIAN)X2] and [Cu(aryl-BIAN)2]X2 as potential laccase biomimetics. An X-ray structural diversity analysis will be presented comparing the results obtained by mechanochemistry with those reached by conventional solution-based methods, as well as their ability to oxidate phenols to quinones.
Original languageEnglish
Publication statusPublished - Mar 2022
EventLatin American Symposium on Coordination and Organometallic Chemistry -
Duration: 10 Mar 202211 Mar 2022
Conference number: 8th
https://silqcom08.navus.io/1180/page/home

Conference

ConferenceLatin American Symposium on Coordination and Organometallic Chemistry
Abbreviated titleSILQCOM08
Period10/03/2211/03/22
Internet address

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