Association constants for the ion pairs formed between [Co(Sep)]3+ and the anions fluoride, chloride, bromide, iodide, perchlorate, and oxalate were obtained from the chemical shifts of the Co-59 resonance that occur upon addition of such anions to solutions of the cobalt complex. The usefulness of Co-59 NMR to obtain formation constants, in order to calculate the "true" quantum yields for the ion pairs, is discussed.
|Journal||Canadian Journal Of Chemistry-Revue Canadienne De Chimie|
|Publication status||Published - Mar 1991|
- ASSOCIATION CONSTANT
- COBALT SEPULCHRATE
- ION PAIR
- CO-59 NMR
- QUANTUM YIELD