TY - JOUR
T1 - Aggregation behavior and total miscibility of fluorinated ionic liquids in water
AU - Pereiro, Ana B.
AU - Araújo, João M M
AU - Teixeira, Fabiana S.
AU - Marrucho Ferreira, Isabel Maria
AU - Piñeiro, Manuel M.
AU - Rebelo, Luis Paulo N
PY - 2015/2/3
Y1 - 2015/2/3
N2 - In this work, novel and nontoxic fluorinated ionic liquids (FILs) that are totally miscible in water and could be used in biological applications, where fluorocarbon compounds present a handicap because their aqueous solubility (water and biological fluids) is in most cases too low, have been investigated. The self-aggregation behavior of perfluorosulfonate-functionalized ionic liquids in aqueous solutions has been characterized using conductometric titration, isothermal titration calorimetry (ITC), surface tension measurements, dynamic light scattering (DLS), viscosity and density measurements, and transmission electron microscopy (TEM). Aggregation and interfacial parameters have been computed by conductimetry, calorimetry, and surface tension measurements in order to study various thermodynamic and surface properties that demonstrate that the aggregation process is entropy-driven and that the aggregation process is less spontaneous than the adsorption process. The novel perfluorosulfonate-functionalized ILs studied in this work show improved surface activity and aggregation behavior, forming distinct self-assembled structures.
AB - In this work, novel and nontoxic fluorinated ionic liquids (FILs) that are totally miscible in water and could be used in biological applications, where fluorocarbon compounds present a handicap because their aqueous solubility (water and biological fluids) is in most cases too low, have been investigated. The self-aggregation behavior of perfluorosulfonate-functionalized ionic liquids in aqueous solutions has been characterized using conductometric titration, isothermal titration calorimetry (ITC), surface tension measurements, dynamic light scattering (DLS), viscosity and density measurements, and transmission electron microscopy (TEM). Aggregation and interfacial parameters have been computed by conductimetry, calorimetry, and surface tension measurements in order to study various thermodynamic and surface properties that demonstrate that the aggregation process is entropy-driven and that the aggregation process is less spontaneous than the adsorption process. The novel perfluorosulfonate-functionalized ILs studied in this work show improved surface activity and aggregation behavior, forming distinct self-assembled structures.
UR - http://www.scopus.com/inward/record.url?scp=84922273433&partnerID=8YFLogxK
U2 - 10.1021/la503961h
DO - 10.1021/la503961h
M3 - Article
AN - SCOPUS:84922273433
SN - 0743-7463
VL - 31
SP - 1283
EP - 1295
JO - Langmuir
JF - Langmuir
IS - 4
ER -