Adsorption of SO2 using vanadium and vanadium-copper supported on activated carbon

Sónia A. C. Carabineiro; Ana M. Ramos; Joaquim Vital; José Miguel Loureiro; José J. de Melo Órfão; Isabel M. Fonseca

doi:10.1016/S0920-5861(02)00335-8

Adsorption of SO₂ using vanadium and vanadium-copper supported on activated carbon

Sónia A. C. Carabineiro, Ana M. Ramos, Joaquim Vital, José Miguel Loureiro, José J. de Melo Órfão, Isabel M. Fonseca

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

Activated carbon impregnated with precursor salts of Ba, Co, Cu, Fe, Mg, Mn, Ni, Pb and V and their binary mixtures was used for adsorption of SO₂ at 20°C. The most promising materials for SO₂ removal are carbons doped with V, Cu and mainly their binary mixtures, which show a synergetic effect. Kinetic curves and isotherms of SO₂ adsorption were obtained at 20°C. These isotherms are reasonably well fitted by the Langmuir model and the respective parameters were determined. TPD experiments show that adsorption of SO₂ increases the oxygenated groups on the carbon surface. The sample doped with V, after SO₂ adsorption at 20°C, presents an increase of basic oxygenated groups, which may be responsible for the observed extra adsorption of SO₂.

Original language	English
Pages (from-to)	203-210
Number of pages	8
Journal	Catalysis Today
Volume	78
Issue number	1-4 SPEC.
DOIs	https://doi.org/10.1016/S0920-5861(02)00335-8
Publication status	Published - 28 Feb 2003

Keywords

Activated carbon
Equilibrium
Kinetics
SO adsorption
TPD

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10.1016/S0920-5861(02)00335-8Licence: CC BY-NC-ND

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@article{2f18994f25404794b1606e4a6c8f3c36,

title = "Adsorption of SO2 using vanadium and vanadium-copper supported on activated carbon",

abstract = "Activated carbon impregnated with precursor salts of Ba, Co, Cu, Fe, Mg, Mn, Ni, Pb and V and their binary mixtures was used for adsorption of SO2 at 20°C. The most promising materials for SO2 removal are carbons doped with V, Cu and mainly their binary mixtures, which show a synergetic effect. Kinetic curves and isotherms of SO2 adsorption were obtained at 20°C. These isotherms are reasonably well fitted by the Langmuir model and the respective parameters were determined. TPD experiments show that adsorption of SO2 increases the oxygenated groups on the carbon surface. The sample doped with V, after SO2 adsorption at 20°C, presents an increase of basic oxygenated groups, which may be responsible for the observed extra adsorption of SO2.",

keywords = "Activated carbon, Equilibrium, Kinetics, SO adsorption, TPD",

author = "Carabineiro, \{S{\'o}nia A. C.\} and Ramos, \{Ana M.\} and Joaquim Vital and Loureiro, \{Jos{\'e} Miguel\} and {\'O}rf{\~a}o, \{Jos{\'e} J. de Melo\} and Fonseca, \{Isabel M.\}",

note = "S{\'o}nia Carabineiro acknowledges financial support from Funda{\c c}{\~a}o para a Ci{\^e}ncia e Tecnologia, grant BD1275/95.",

year = "2003",

month = feb,

day = "28",

doi = "10.1016/S0920-5861(02)00335-8",

language = "English",

volume = "78",

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TY - JOUR

T1 - Adsorption of SO2 using vanadium and vanadium-copper supported on activated carbon

AU - Carabineiro, Sónia A. C.

AU - Ramos, Ana M.

AU - Vital, Joaquim

AU - Loureiro, José Miguel

AU - Órfão, José J. de Melo

AU - Fonseca, Isabel M.

N1 - Sónia Carabineiro acknowledges financial support from Fundação para a Ciência e Tecnologia, grant BD1275/95.

PY - 2003/2/28

Y1 - 2003/2/28

N2 - Activated carbon impregnated with precursor salts of Ba, Co, Cu, Fe, Mg, Mn, Ni, Pb and V and their binary mixtures was used for adsorption of SO2 at 20°C. The most promising materials for SO2 removal are carbons doped with V, Cu and mainly their binary mixtures, which show a synergetic effect. Kinetic curves and isotherms of SO2 adsorption were obtained at 20°C. These isotherms are reasonably well fitted by the Langmuir model and the respective parameters were determined. TPD experiments show that adsorption of SO2 increases the oxygenated groups on the carbon surface. The sample doped with V, after SO2 adsorption at 20°C, presents an increase of basic oxygenated groups, which may be responsible for the observed extra adsorption of SO2.

AB - Activated carbon impregnated with precursor salts of Ba, Co, Cu, Fe, Mg, Mn, Ni, Pb and V and their binary mixtures was used for adsorption of SO2 at 20°C. The most promising materials for SO2 removal are carbons doped with V, Cu and mainly their binary mixtures, which show a synergetic effect. Kinetic curves and isotherms of SO2 adsorption were obtained at 20°C. These isotherms are reasonably well fitted by the Langmuir model and the respective parameters were determined. TPD experiments show that adsorption of SO2 increases the oxygenated groups on the carbon surface. The sample doped with V, after SO2 adsorption at 20°C, presents an increase of basic oxygenated groups, which may be responsible for the observed extra adsorption of SO2.

KW - Activated carbon

KW - Equilibrium

KW - Kinetics

KW - SO adsorption

KW - TPD

UR - https://www.scopus.com/pages/publications/0037469461

U2 - 10.1016/S0920-5861(02)00335-8

DO - 10.1016/S0920-5861(02)00335-8

M3 - Article

AN - SCOPUS:0037469461

SN - 0920-5861

VL - 78

SP - 203

EP - 210

JO - Catalysis Today

JF - Catalysis Today

IS - 1-4 SPEC.

ER -

Adsorption of SO₂ using vanadium and vanadium-copper supported on activated carbon

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Keywords

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