TY - JOUR
T1 - Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint
AU - Rebelo, Luís Paulo N.
AU - Lopes, José N. Canongia
AU - Esperança, José M. S. S.
AU - Guedes, Henrique J. R.
AU - Łachwa, Joanna
AU - Najdanovic-Visak, Vesna
AU - Visak, Zoran P.
PY - 2007/11/1
Y1 - 2007/11/1
N2 - The fascinating, complex behavior of ionic liquids is analyzed using a molecular perspective that emphasizes the doubly dual nature of ionic liquids underlying the existence of cations and anions forming high- and low-charge-density regions. Our work bridges the liquid, gas, and solid phases spanning 5 years of research on themes as diverse as the vaporization, liquid-liquid demixing, solidification, and thermophysical behavior of ionic liquids and their mixtures and solutions.
AB - The fascinating, complex behavior of ionic liquids is analyzed using a molecular perspective that emphasizes the doubly dual nature of ionic liquids underlying the existence of cations and anions forming high- and low-charge-density regions. Our work bridges the liquid, gas, and solid phases spanning 5 years of research on themes as diverse as the vaporization, liquid-liquid demixing, solidification, and thermophysical behavior of ionic liquids and their mixtures and solutions.
KW - Ionic liquids
KW - Binary mixtures
KW - Pure ionic
UR - http://www.scopus.com/inward/record.url?scp=36749086203&partnerID=8YFLogxK
U2 - 10.1021/ar7000556
DO - 10.1021/ar7000556
M3 - Article
C2 - 17622178
AN - SCOPUS:36749086203
SN - 0001-4842
VL - 40
SP - 1114
EP - 1121
JO - Accounts of Chemical Research
JF - Accounts of Chemical Research
IS - 11
ER -